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C2 symmetrical nickel complexes derived from a-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes

Escorihuela Fuentes, Jorge; Altava Benito, Belén; Burguete Azcarate, Mª Isabel; Luis Lafuente, Santiago (Elsevier, 2013-01-14)

[EN] A series of C2 symmetrical 1:2 Ni:L complexes derived from a-amino amides were studied for the enantioselective addition of dialkylzinc reagents to aldehydes. Different structural elements on the ligands seem to play ...
Gold(III) stabilized over ionic liquids grafted on MCM-41 for highly efficient three component coupling reactions

Bobadilla, Luis F; Blasco Lanzuela, Teresa; Odriozola, José Antonio (Royal Society of Chemistry, 2013)

[EN] Two alkoxysilyl-modified ionic liquids (ILs) have been synthesized and further grafted onto mesoporous silica, MCM-41; these ionic liquids were used for dispersing AuCl3 catalysts that activate C-H bonds as required ...

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