Corma Canós, Avelino; Juárez Marín, Raquel; Boronat Zaragoza, Mercedes; Sánchez, Félix; Iglesias, Marta; García Gómez, Hermenegildo(Royal Society of Chemistry, 2011)
[EN] By a combination of kinetic and theoretical studies it is concluded that gold is intrinsically active to perform the Sonogashira coupling reaction between phenylacetylene and iodobenzene. The presence of Pd impurities ...
Metal-catalysed chemical reactions are often controlled by steric hindrance around the metal atom and it is rare that substituents far away of the reaction site could be differentiated during reaction, particularly if they ...