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The first zeolite with a tri-directional extra-large 14-ring pore system derived using a phosphonium-based organic molecule

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The first zeolite with a tri-directional extra-large 14-ring pore system derived using a phosphonium-based organic molecule

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dc.contributor.author Yun, Yifeng es_ES
dc.contributor.author Hernández Rodríguez, Manuel es_ES
dc.contributor.author Wan, Wei es_ES
dc.contributor.author Zou, Xiaodong es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Cantin Sanz, Angel es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2018-09-17T07:06:11Z
dc.date.available 2018-09-17T07:06:11Z
dc.date.issued 2015 es_ES
dc.identifier.issn 1359-7345 es_ES
dc.identifier.uri http://hdl.handle.net/10251/107348
dc.description.abstract [EN] A new germanosilicate zeolite (denoted as ITQ-53) with extra-large pores has been synthesised using tri-tertbutylmethylphosphonium cation as the organic structure directing agent (OSDA). Rotation electron diffraction (RED) was used to identify ITQ-53 from an initially-synthesised sample containing impurities, and to solve its structure. The structure was refined against PXRD data of pure ITQ-53 samples obtained after synthesis optimisation. ITQ-53 is the first example of extra-large pore zeolites with tri-directional interconnected 14 x 14 x 14-ring channels. It is stable up to at least 650 degrees C. The structure of ITQ-53 changes from monoclinic to orthorhombic upon calcination. es_ES
dc.description.sponsorship This work was supported by the Spanish Government (MAT2012-38567-C02-01, Consolider Ingenio 2010-Multicat CSD-2009-00050 and Severo Ochoa SEV-2012-0267), the Swedish Research Council (VR), the Swedish Governmental Agency for Innovation Systems (VINNOVA) and the Knut & Alice Wallenberg Foundation through a grant for purchasing the TEMs and the project grant 3DEM-NATUR. Yifeng Yun thanks the China Scholarship Council (CSC). es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Communications es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title The first zeolite with a tri-directional extra-large 14-ring pore system derived using a phosphonium-based organic molecule es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4cc10317c es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2012-38567-C02-01/ES/MATERIALES ZEOLITICOS COMO ESTRUCTURAS ANFITRIONAS DE NANOPARTICULAS. SINTESIS Y APLICACIONES NANOTECNOLOGICAS, CATALITICAS Y MEDIOAMBIENTALES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/ES/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Yun, Y.; Hernández Rodríguez, M.; Wan, W.; Zou, X.; Jorda Moret, JL.; Cantin Sanz, A.; Rey Garcia, F.... (2015). The first zeolite with a tri-directional extra-large 14-ring pore system derived using a phosphonium-based organic molecule. Chemical Communications. 51(36):7602-7605. https://doi.org/10.1039/c4cc10317c es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c4cc10317c es_ES
dc.description.upvformatpinicio 7602 es_ES
dc.description.upvformatpfin 7605 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 51 es_ES
dc.description.issue 36 es_ES
dc.relation.pasarela S\306438 es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Swedish Research Council Formas
dc.contributor.funder Swedish Governmental Agency for Innovation Systems
dc.contributor.funder Knut and Alice Wallenberg Foundation
dc.contributor.funder China Scholarship Council
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