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dc.contributor.author | Van der Perre, Stijn | es_ES |
dc.contributor.author | Gelin, Pierre | es_ES |
dc.contributor.author | Claessens, Benjamin | es_ES |
dc.contributor.author | Martin-Calvo, Ana | es_ES |
dc.contributor.author | Saint Remi, Julien Cousin | es_ES |
dc.contributor.author | Duerinck, Tim | es_ES |
dc.contributor.author | Baron, Gino V. | es_ES |
dc.contributor.author | Palomino Roca, Miguel | es_ES |
dc.contributor.author | Sánchez, Ledys Yelitza | es_ES |
dc.contributor.author | Valencia Valencia, Susana | es_ES |
dc.contributor.author | Shang, Jin | es_ES |
dc.contributor.author | Singh, Ranjeet | es_ES |
dc.contributor.author | Webley, Paul A. | es_ES |
dc.contributor.author | Rey Garcia, Fernando | es_ES |
dc.contributor.author | Denayer, Joeri F. M. | es_ES |
dc.date.accessioned | 2018-11-01T05:33:42Z | |
dc.date.available | 2018-11-01T05:33:42Z | |
dc.date.issued | 2017 | es_ES |
dc.identifier.issn | 1864-5631 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/111688 | |
dc.description.abstract | [EN] A vapor phase adsorptive recovery process is proposed as an alternative way to isolate biobutanol from acetone-butanolethanol (ABE) fermentation media, offering several advantages compared to liquid phase separation. The effect of water, which is still present in large quantities in vapor phase, on the adsorption of the organics could be minimized by using hydrophobic zeolites. Shape selective all-silica zeolites CHA and LTA were prepared and evaluated via single component isotherms and breakthrough experiments. These zeolites show an opposite selectivity; adsorption of ethanol was favorable on all-silica CHA, while the LTA topology had clear preference for butanol. The molecular sieving properties of both zeolites allowed to easily eliminate acetone from the mixture. The molecular interaction mechanisms were studied by density functional theory (DFT) simulations. Effect of mixture composition, humidity and total pressure of the vapor stream on the selectivity and separation behavior was investigated. Desorption profiles were studied to maximize butanol purity and recovery. The combination of LTA with CHA type zeolites (Si-CHA or SAPO-34) in sequential adsorption columns with alternating adsorption and desorption steps allows to obtain butanol in unpreceded purity and recovery. A butanol purity of 99.7 mole% could be obtained at nearly complete butanol recovery, demonstrating the effectiveness of this technique for biobutanol separation processes. | es_ES |
dc.description.sponsorship | S.V.D.P. and J.F.M.D. are grateful to FWO Vlaanderen for financial support (G025614N). M.P., L.Y.S., S.V. and F.R. gratefully acknowledge financial support of Spanish Government (MAT2015-71842P and Severo Ochoa SEV-2012-0267). The authors thank to A. Vidal and T. Blasco for performing NMR measurements and discussion. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | ChemSusChem | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Adsorption | es_ES |
dc.subject | Biobutanol | es_ES |
dc.subject | Biorefineries | es_ES |
dc.subject | Downstream processing | es_ES |
dc.subject | Zeolites | es_ES |
dc.title | Intensified biobutanol recovery using zeolites with complementary selectivity | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/cssc.201700667 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Van Der Perre, S.; Gelin, P.; Claessens, B.; Martin-Calvo, A.; Saint Remi, JC.; Duerinck, T.; Baron, GV.... (2017). Intensified biobutanol recovery using zeolites with complementary selectivity. ChemSusChem. 10(14):2968-2977. https://doi.org/10.1002/cssc.201700667 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1002/cssc.201700667 | es_ES |
dc.description.upvformatpinicio | 2968 | es_ES |
dc.description.upvformatpfin | 2977 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 10 | es_ES |
dc.description.issue | 14 | es_ES |
dc.relation.pasarela | S\339069 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |