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Functional Ag-Exchanged Zeolites as Biocide Agents

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Functional Ag-Exchanged Zeolites as Biocide Agents

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dc.contributor.author Cerrillo, José Luis es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Pérez-Gago, María B. es_ES
dc.contributor.author Villamón-Pérez, Diana es_ES
dc.contributor.author Palou-Valls, Lluis es_ES
dc.date.accessioned 2020-06-04T06:30:19Z
dc.date.available 2020-06-04T06:30:19Z
dc.date.issued 2018-05-02 es_ES
dc.identifier.uri http://hdl.handle.net/10251/145194
dc.description "This is the peer reviewed version of the following article: Cerrillo, José Luis, Antonio Eduardo Palomares, Fernando Rey, Susana Valencia, María Bernardita Pérez-Gago, Diana Villamón, and Lluís Palou. 2018. Functional Ag-Exchanged Zeolites as Biocide Agents. ChemistrySelect 3 (17). Wiley: 4676 82. doi:10.1002/slct.201800432, which has been published in final form at https://doi.org/10.1002/slct.201800432. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] Materials based on silver are used for controlling different pathogenic microorganisms. However, the influence of the silver carrier in the biocidal activity of the material has been scarcely reported. The present research is focused on studying the influence of zeolite properties on the biocidal activity of silver-exchanged zeolites, acting as reservoirs of silver species. The biocidal action of Ag-Faujasite (Ag-FAU) and Ag-Linde Type A (Ag-LTA) zeolites, containing different silver contents, is studied against different types of bacteria and fungi. Importantly, zeolite structure is found to be a significant parameter for controlling the antibacterial activity of Ag-exchanged zeolites. The results show that Ag-FAU presents a higher activity than Ag-LTA, because the topology of FAU combined with its highest Si/Al ratio favors the formation and release of silver species with important biocidal activity. Some insights on the bactericidal mechanism of Ag-zeolites are envisaged by means of high resolution transmission electron microscopy, showing the multi-targeted biocidal action of Ag species released from zeolites. Besides, it is shown that Ag-zeolites are more active against bacteria than fungi. Antifungal activity is highly dependent on the fungi species and the structure of the zeolite is not as determinant as it is for the antibacterial activity. es_ES
dc.description.sponsorship The authors thank the Spanish Ministry of Economy and Competitiveness through MAT-2015-71842-P and SEV-2016-0683 for the financial support and J.L. Cerrillo wish to thank Spanish Ministry of Economy and Competitiveness for the Severo Ochoa PhD fellowship (SVP-2014-068600). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemistrySelect es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Bactericides es_ES
dc.subject Biocidal materials es_ES
dc.subject Fungicides es_ES
dc.subject Silver es_ES
dc.subject Zeolites es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Functional Ag-Exchanged Zeolites as Biocide Agents es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/slct.201800432 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068600/ES/SVP-2014-068600/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Cerrillo, JL.; Palomares Gimeno, AE.; Rey Garcia, F.; Valencia Valencia, S.; Pérez-Gago, MB.; Villamón-Pérez, D.; Palou-Valls, L. (2018). Functional Ag-Exchanged Zeolites as Biocide Agents. ChemistrySelect. 3(17):4676-4682. https://doi.org/10.1002/slct.201800432 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/slct.201800432 es_ES
dc.description.upvformatpinicio 4676 es_ES
dc.description.upvformatpfin 4682 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 3 es_ES
dc.description.issue 17 es_ES
dc.identifier.eissn 2365-6549 es_ES
dc.relation.pasarela S\369882 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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