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Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance

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Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance

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dc.contributor.author Gallego-Sánchez, Eva María es_ES
dc.contributor.author Li, Chengeng es_ES
dc.contributor.author Paris, Cecilia es_ES
dc.contributor.author Martín-García, Nuria es_ES
dc.contributor.author Martínez-Triguero, Joaquín es_ES
dc.contributor.author Boronat Zaragoza, Mercedes es_ES
dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2020-06-12T03:34:19Z
dc.date.available 2020-06-12T03:34:19Z
dc.date.issued 2018-10-01 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/146189
dc.description.abstract [EN] From theoretical calculations and a rational synthesis methodology, it has been possible to prepare nanocrystalline (60-80 nm) chabazite with an optimized framework Al distribution that has a positive impact on its catalytic properties. This is exemplified for the methanol-to-olefin (MTO) process. The nanosized material with the predicted Al distribution maximizes the formation of the required MTO hydrocarbon pool intermediates, while better precluding excessive diffusion pathways that favor the rapid catalyst deactivation by coke formation. es_ES
dc.description.sponsorship This work has been supported by the EU through ERC-AdG-2014-671093, by the Spanish Government-MINECO through "Severo Ochoa" (SEV-2016-0683) and MAT2015-71261-R, and by the Fundacion Ramon Areces through a research contract of the "Life and Materials Science" program. E.M.G. acknowledges "La Caixa-Severo Ochoa" International PhD Fellowships (call 2015), C.L. acknowledges China Scholarship Council (CSC) for a Ph.D fellowship, and N.M. thanks MINECO for a pre-doctoral fellowship (BES-2013-064347). Red Espanola de Supercomputacion (RES) and Centre de Calcul de la Universitat de Valencia are gratefully acknowledged for computational resources. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Aluminum es_ES
dc.subject Chabazite es_ES
dc.subject Light olefins es_ES
dc.subject Methanol-to-olefin process es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201803637 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71261-R/ES/DISEÑO RACIONAL DE MATERIALES ZEOLITICOS CON CENTROS METALICOS PARA SU APLICACION EN PROCESOS QUIMICOS SOSTENIBLES, MEDIOAMBIENTALES Y ENERGIAS RENOVABLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//BES-2013-064347/ES/BES-2013-064347/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gallego-Sánchez, EM.; Li, C.; Paris, C.; Martín-García, N.; Martínez-Triguero, J.; Boronat Zaragoza, M.; Moliner Marin, M.... (2018). Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance. Chemistry - A European Journal. 24(55):14631-14635. https://doi.org/10.1002/chem.201803637 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201803637 es_ES
dc.description.upvformatpinicio 14631 es_ES
dc.description.upvformatpfin 14635 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 24 es_ES
dc.description.issue 55 es_ES
dc.relation.pasarela S\370570 es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder China Scholarship Council es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Fundació Bancària Caixa d'Estalvis i Pensions de Barcelona es_ES
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