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Pressure Effect Studies on the 3D Spin Crossover System: {Fe(3CN-py)2[M(CN)2]2}·nH2O (n < 2/3, M = Ag(I), Au(I))

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Pressure Effect Studies on the 3D Spin Crossover System: {Fe(3CN-py)2[M(CN)2]2}·nH2O (n < 2/3, M = Ag(I), Au(I))

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dc.contributor.author Galet, A es_ES
dc.contributor.author Gaspar, A. B. es_ES
dc.contributor.author Agusti, G. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.contributor.author Real, J. A. es_ES
dc.date.accessioned 2020-09-25T03:30:34Z
dc.date.available 2020-09-25T03:30:34Z
dc.date.issued 2007-01-26 es_ES
dc.identifier.issn 0009-2614 es_ES
dc.identifier.uri http://hdl.handle.net/10251/150715
dc.description.abstract [EN] Pressure effect investigations on the magnetic behaviour of the 3D SCO polymers {Fe(3CN-py)2[Ag(CN)2]2} · 2/3H2O (1) and {Fe(3CN-py)2[Au(CN)2]2} · 2/3H2O (2) have been carried out in the range of 105 Pa to 0.7 GPa. Despite both compounds are isostructural their magnetic behaviour under applied hydrostatic pressures is very different. Strong nonlinearity in the Tc(P) vs. P plot has been observed for compound 1 a fact which contrasts with the almost linear dependence observed for each spin transition in 2. However, both compounds are extremely sensitive to the application of pressure as well as the Tc(P) vs. P plots denote. es_ES
dc.description.sponsorship Financial support is acknowledged from the Spanish Ministerio de Educación y Ciencia (MEC) (CTQ 2004 03456/BQU) and from the Generalitat Valenciana for the Research Grant ACOMP06/048. A.G. thanks the Universitat Politècnica de València for a predoctoral fellowship. A.B.G. thanks the Spanish MEC for a Research Contract (Programa Ramón y Cajal). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Chemical Physics Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Pressure Effect Studies on the 3D Spin Crossover System: {Fe(3CN-py)2[M(CN)2]2}·nH2O (n < 2/3, M = Ag(I), Au(I)) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.cplett.2006.11.087 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//CTQ2004-03456/ES/TRANSICION DE ESPIN EN MATERIALES MAGNETICOS FUNCIONALES DE BASE MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACOMP06%2F048/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Galet, A.; Gaspar, AB.; Agusti, G.; Muñoz Roca, MDC.; Real, JA. (2007). Pressure Effect Studies on the 3D Spin Crossover System: {Fe(3CN-py)2[M(CN)2]2}·nH2O (n < 2/3, M = Ag(I), Au(I)). Chemical Physics Letters. 434(1-3):68-72. https://doi.org/10.1016/j.cplett.2006.11.087 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.cplett.2006.11.087 es_ES
dc.description.upvformatpinicio 68 es_ES
dc.description.upvformatpfin 72 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 434 es_ES
dc.description.issue 1-3 es_ES
dc.relation.pasarela S\230648 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
dc.contributor.funder Universitat Politècnica de València es_ES


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