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Synthesis of 2D and 3D MOFs with tuneable Lewis acidity from preformed 1D hybrid sub-domains

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Synthesis of 2D and 3D MOFs with tuneable Lewis acidity from preformed 1D hybrid sub-domains

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dc.contributor.author Moreno-Rodríguez, José María es_ES
dc.contributor.author Velty, Alexandra es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2020-11-17T04:32:13Z
dc.date.available 2020-11-17T04:32:13Z
dc.date.issued 2019-02-21 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155120
dc.description.abstract [EN] Novel MOF-type materials with different morphologies based on assembled 1D organic-inorganic subdomains were prepared using specific monodentate benzylcarboxylate spacers with functional substituents in the para-position as structure modulating agents. The combination of electronwithdrawing or electron-donating functions in the organic spacers with suitable solvothermal synthesis conditions allowed modulating the structuration level (2D or 3D), vacancies, physico-chemical properties and Lewis acidity strength of the metal-organic structures. Furthermore, bimetallic (Al/ Fe) MOF-type materials were synthesized by a one-pot direct process without modification of the structural framework. The activity of these hybrid materials as Lewis acid catalysts was evaluated to prepare cyanohydrins as precursors for the synthesis of biologically active compounds, and for aerobic oxidation of thiols to disulfides. The catalytic results showed that the derived MOFs exhibited modulatable Lewis acid capacities which are a function of the morphology, functionality of monodentate substituents present in the networks and a cooperative effect between metallic nodes of different nature. es_ES
dc.description.sponsorship The authors are grateful for financial support from the Spanish Government by MAT2014-52085-C2-1-P, MAT2017-82288-C2-1-P and Severo Ochoa Excellence Program SEV-2016-0683. J. M. M. acknowledges Predoctoral Fellowships from MINECO for economical support. The authors thank the MULTY2HYCAT (EU-Horizon 2020 funded project under grant agreement no. 720783). The European Union is also acknowledged by ERC-AdG-2014-671093-SynCatMatch. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento - No comercial (by-nc) es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Synthesis of 2D and 3D MOFs with tuneable Lewis acidity from preformed 1D hybrid sub-domains es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c8sc04372h es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/720783/EU/MULTI-site organic-inorganic HYbrid CATalysts for MULTI-step chemical processes/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-52085-C2-1-P/ES/NUEVOS MATERIALES CON DIFERENTES CENTROS ACTIVOS INCORPORADOS EN POSICIONES ESPECIFICAS DE LA RED Y SU APLICACION PARA PROCESOS CATALITICOS MULTI-ETAPA Y NANOTECNOLOGICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Moreno-Rodríguez, JM.; Velty, A.; Díaz Morales, UM.; Corma Canós, A. (2019). Synthesis of 2D and 3D MOFs with tuneable Lewis acidity from preformed 1D hybrid sub-domains. Chemical Science. 10(7):2053-2066. https://doi.org/10.1039/c8sc04372h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c8sc04372h es_ES
dc.description.upvformatpinicio 2053 es_ES
dc.description.upvformatpfin 2066 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 7 es_ES
dc.identifier.pmid 30842863 es_ES
dc.identifier.pmcid PMC6375358 es_ES
dc.relation.pasarela S\407665 es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder European Commission
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