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Manufacturing and Properties of Binary Blend from Bacterial Polyester Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) and Poly(caprolactone) with Improved Toughness

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Manufacturing and Properties of Binary Blend from Bacterial Polyester Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) and Poly(caprolactone) with Improved Toughness

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dc.contributor.author Ivorra-Martínez, Juan es_ES
dc.contributor.author Verdu, Isabel es_ES
dc.contributor.author Fenollar, Octavio es_ES
dc.contributor.author Sanchez-Nacher, Lourdes es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.date.accessioned 2021-03-01T08:09:29Z
dc.date.available 2021-03-01T08:09:29Z
dc.date.issued 2020-05 es_ES
dc.identifier.uri http://hdl.handle.net/10251/162589
dc.description.abstract [EN] Polyhydroxyalkanoates (PHAs) represent a promising group of bacterial polyesters for new applications. Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) is a very promising bacterial polyester with potential uses in the packaging industry; nevertheless, as with many (almost all) bacterial polyesters, PHBH undergoes secondary crystallization (aging) which leads to an embrittlement. To overcome or minimize this, in the present work a flexible petroleum-derived polyester, namely poly(e-caprolactone), was used to obtain PHBH/PCL blends with different compositions (from 0 to 40 PCL wt %) using extrusion followed by injection moulding. The thermal analysis of the binary blends was studied by means of differential scanning calorimetry (DSC) and thermogravimetry (TGA). Both TGA and DSC revealed immiscibility between PHBH and PCL. Mechanical dynamic thermal analysis (DMTA) allowed a precise determination of the glass transition temperatures (Tg) as a function of the blend composition. By means of field emission scanning electron microscopy (FESEM), an internal structure formed by two phases was observed, with a PHBH-rich matrix phase and a finely dispersed PCL-rich phase. These results confirmed the immiscibility between these two biopolymers. However, the mechanical properties obtained through tensile and Charpy tests, indicated that the addition of PCL to PHBH considerably improved toughness. PHBH/PCL blends containing 40 PCL wt % offered an impact resistance double that of neat PHBH. PCL addition also contributed to a decrease in brittleness and an improvement in toughness and some other ductile properties. As expected, an increase in ductile properties resulted in a decrease in some mechanical resistant properties, e.g., the modulus and the strength (in tensile and flexural conditions) decreased with increasing wt % PCL in PHBH/PCL blends. es_ES
dc.description.sponsorship This research work was funded by the Spanish Ministry of Science, Innovation, and Universities (MICIU), project numbers MAT2017-84909-C2-2-R. This work was supported by the POLISABIO program, grant number (2019-A02). Juan Ivorra-Martinez is the recipient of an FPI grant from Universitat Politècnica de València (PAID-2019-SP20190011). Luis Quiles-Carrillo wants to thank GVA for his FPI grant (ACIF/2016/182) and MECD for his FPU grant (FPU15/03812). Microscopy services at UPV are acknowledged for their help in collecting and analyzing FESEM images. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Bacterial polyesters es_ES
dc.subject Poly(3-hydroxybutyrate-co-3hydroxyhexanoate)-PHBH es_ES
dc.subject Poly(e-caprolactone)-PCL es_ES
dc.subject Binary blends es_ES
dc.subject Improved toughness es_ES
dc.subject Mechanical and thermal characterization es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Manufacturing and Properties of Binary Blend from Bacterial Polyester Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) and Poly(caprolactone) with Improved Toughness es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym12051118 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//PAID-2019-SP20190011/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2016%2F182/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UPV//UPV-FISABIO-2019-A02/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Ivorra-Martínez, J.; Verdu, I.; Fenollar, O.; Sanchez-Nacher, L.; Balart, R.; Quiles-Carrillo, L. (2020). Manufacturing and Properties of Binary Blend from Bacterial Polyester Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) and Poly(caprolactone) with Improved Toughness. Polymers. 12(5):1-20. https://doi.org/10.3390/polym12051118 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/polym12051118 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 20 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 5 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.identifier.pmid 32422915 es_ES
dc.identifier.pmcid PMC7285169 es_ES
dc.relation.pasarela S\413131 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Fundación para el Fomento de la Investigación Sanitaria y Biomédica de la Comunitat Valenciana es_ES
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dc.subject.ods 12.- Garantizar las pautas de consumo y de producción sostenibles es_ES


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