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Modification of poly (lactic acid) through the incorporation of gum rosin and gum rosin derivative: Mechanical performance and hydrophobicity

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Modification of poly (lactic acid) through the incorporation of gum rosin and gum rosin derivative: Mechanical performance and hydrophobicity

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dc.contributor.author Rosa-Ramírez, Harrison de la es_ES
dc.contributor.author Aldás-Carrasco, Miguel Fernando es_ES
dc.contributor.author Ferri, J.M. es_ES
dc.contributor.author López-Martínez, Juan es_ES
dc.contributor.author Samper, María-Dolores es_ES
dc.date.accessioned 2021-03-03T04:31:53Z
dc.date.available 2021-03-03T04:31:53Z
dc.date.issued 2020-11-20 es_ES
dc.identifier.issn 0021-8995 es_ES
dc.identifier.uri http://hdl.handle.net/10251/162862
dc.description "This is the peer reviewed version of the following article: De La Rosa-Ramírez, Harrison, Miguel Aldas, José Miguel Ferri, Juan López-Martínez, and María Dolores Samper. 2020. "Modification of Poly (Lactic Acid) through the Incorporation of Gum Rosin and Gum Rosin Derivative: Mechanical Performance and Hydrophobicity." Journal of Applied Polymer Science 137 (44). Wiley: 49346. doi:10.1002/app.49346, which has been published in final form at https://doi.org/10.1002/app.49346. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] The modification of PLA by melt compound with gum rosin (GR) and pentaerythritol ester of GR (PEGR) was investigated by studying the mechanical and thermal performance, blends morphology, wettability, and water absorption. Standard testing specimens for characterization were made at a variate resin content of 5, 10, and 15 part per hundred resin (phr) and manufactured by injection molding. It was found that GR and PEGR had a lubricating effect in PLA polymeric chains, resulting in a remarkable increase of 790 and 193% in melt flow index with only 5 phr GR and PEGR contents, respectively. A significant change in more than 10 degrees of increasing water contact angle was observed for PLA with 15 phr PEGR. Thermogravimetric analysis reveals that PEGR led to delayed PLA degradation/decomposition process to higher temperature, increasing the onset temperature (T-5%) in more than 7 degrees C for PLA with 15 phr PEGR. es_ES
dc.description.sponsorship This research was supported by the Ministry of Economy and Competitiveness-PROMADEPCOL Ref: (MAT2017-84909-C2-2-R). Authors also want to acknowledge the postdoc contract offered to José Miguel Ferri by the Generalitat Valenciana, which project title is "BIONANOCOMPOSITES BASADOS EN MEZCLAS DE PLA Y TPS CON MEMORIA" (APOSTD/2019/122) GENERALITAT VALENCIANA (2019-2021). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Colophony es_ES
dc.subject Gum rosin es_ES
dc.subject Pentaerythritol ester of gum rosin es_ES
dc.subject Poly (lactic acid) es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Modification of poly (lactic acid) through the incorporation of gum rosin and gum rosin derivative: Mechanical performance and hydrophobicity es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.49346 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//APOSTD%2F2019%2F122/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Rosa-Ramírez, HDL.; Aldás-Carrasco, MF.; Ferri, J.; López-Martínez, J.; Samper, M. (2020). Modification of poly (lactic acid) through the incorporation of gum rosin and gum rosin derivative: Mechanical performance and hydrophobicity. Journal of Applied Polymer Science. 137(44):1-15. https://doi.org/10.1002/app.49346 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/app.49346 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 15 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 137 es_ES
dc.description.issue 44 es_ES
dc.relation.pasarela S\412462 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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