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CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size

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CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size

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dc.contributor.author García-Hurtado, Elisa es_ES
dc.contributor.author Rodríguez-Fernández, Aida es_ES
dc.contributor.author Moliner Marin, Manuel es_ES
dc.contributor.author Martínez, Cristina es_ES
dc.date.accessioned 2021-04-20T03:31:00Z
dc.date.available 2021-04-20T03:31:00Z
dc.date.issued 2020-08-21 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165356
dc.description.abstract [EN] In the present manuscript, the influence of the zeolite structure and crystal size on bifunctional tandem catalysts combining K-promoted iron oxide (K/Fe3O4) with different zeolites has been studied for the CO(2)hydrogenation reaction at 320 degrees C and 25 bar. First, to evaluate the influence of the zeolite structure on CO(2)conversion, three different zeolite topologies have been evaluated (BEA, MFI and CHA) with similar Si/Al molar ratios. The combination of K/Fe(3)O(4)with MFI maximizes the formation of aromatic products, while its combination with CHA and BEA increases the C-1-C(4)gas fractions, with a high olefin selectivity. In addition, aromatics and aliphatic hydrocarbons are present in the condensed liquids of the tandem catalysts containing BEA, while no aromatics are observed for those with CHA. These different product selectivities can be ascribed to the different consecutive reactions within the three zeolites, where MFI favors the aromatization of alkenes, and BEA and CHA favor oligomerization/cracking reactions leading to an increase of light olefin yield. Second, the evaluation of the nanosized form of the three proposed zeolite frameworks has also been carried out. The reduction of the particle size allows for increasing light olefin selectivity in all cases as compared to zeolites with larger crystals. Shorter intracrystalline diffusion paths facilitate the egression of light olefins before being involved in consecutive oligomerization reactions. In the particular case of the tandem catalysts with nanosized MFI zeolites, the C-2-C(4)fraction and its olefinicity are increased while maintaining the overall aromatic selectivity comparable to that obtained with micron-sized MFI zeolites. es_ES
dc.description.sponsorship This work was supported by the Spanish Government through "Severo Ochoa" (SEV-2016-0683, MINECO) and RTI2018-101033-B-I00 (MCIU/AEI/FEDER, UE), by the Fundacion Ramon Areces through a research contract (CIVP18A3908) and by Generalitat Valenciana (AICO/2019/060). A. R. F. acknowledges the Spanish Government-MINECO for a FPU scholarship (FPU2017/01521). The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/d0cy00712a es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/Fundación Ramón Areces//CIVP18A3908/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F060/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//FPU2017%2F01521/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation García-Hurtado, E.; Rodríguez-Fernández, A.; Moliner Marin, M.; Martínez, C. (2020). CO(2)hydrogenation using bifunctional catalysts based on K-promoted iron oxide and zeolite: influence of the zeolite structure and crystal size. Catalysis Science & Technology. 10(16):5648-5658. https://doi.org/10.1039/d0cy00712a es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/d0cy00712a es_ES
dc.description.upvformatpinicio 5648 es_ES
dc.description.upvformatpfin 5658 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 16 es_ES
dc.relation.pasarela S\427095 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.description.references Höök, M., & Tang, X. (2013). Depletion of fossil fuels and anthropogenic climate change—A review. Energy Policy, 52, 797-809. doi:10.1016/j.enpol.2012.10.046 es_ES
dc.description.references Dincer, I. (2000). Renewable energy and sustainable development: a crucial review. Renewable and Sustainable Energy Reviews, 4(2), 157-175. doi:10.1016/s1364-0321(99)00011-8 es_ES
dc.description.references Kannan, N., & Vakeesan, D. (2016). Solar energy for future world: - A review. Renewable and Sustainable Energy Reviews, 62, 1092-1105. doi:10.1016/j.rser.2016.05.022 es_ES
dc.description.references Corma, A., Iborra, S., & Velty, A. (2007). Chemical Routes for the Transformation of Biomass into Chemicals. Chemical Reviews, 107(6), 2411-2502. doi:10.1021/cr050989d es_ES
dc.description.references Abate, S., Barbera, K., Centi, G., Lanzafame, P., & Perathoner, S. (2016). Disruptive catalysis by zeolites. Catalysis Science & Technology, 6(8), 2485-2501. doi:10.1039/c5cy02184g es_ES
dc.description.references Goeppert, A., Czaun, M., Jones, J.-P., Surya Prakash, G. K., & Olah, G. A. (2014). Recycling of carbon dioxide to methanol and derived products – closing the loop. Chem. Soc. Rev., 43(23), 7995-8048. doi:10.1039/c4cs00122b es_ES
dc.description.references Prieto, G. (2017). Carbon Dioxide Hydrogenation into Higher Hydrocarbons and Oxygenates: Thermodynamic and Kinetic Bounds and Progress with Heterogeneous and Homogeneous Catalysis. ChemSusChem, 10(6), 1056-1070. doi:10.1002/cssc.201601591 es_ES
dc.description.references Dorner, R. W., Hardy, D. R., Williams, F. W., & Willauer, H. D. (2010). Heterogeneous catalytic CO2 conversion to value-added hydrocarbons. Energy & Environmental Science, 3(7), 884. doi:10.1039/c001514h es_ES
dc.description.references Gao, P., Li, S., Bu, X., Dang, S., Liu, Z., Wang, H., … Sun, Y. (2017). Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst. Nature Chemistry, 9(10), 1019-1024. doi:10.1038/nchem.2794 es_ES
dc.description.references WEATHERBEE, G. (1984). Hydrogenation of CO2 on group VIII metals IV. Specific activities and selectivities of silica-supported Co, Fe, and Ru. Journal of Catalysis, 87(2), 352-362. doi:10.1016/0021-9517(84)90196-9 es_ES
dc.description.references Lee, M.-D., Lee, J.-F., Chang, C.-S., & Dong, T.-Y. (1991). Effects of addition of chromium, manganese, or molybdenum to iron catalysts for carbon dioxide hydrogenation. Applied Catalysis, 72(2), 267-281. doi:10.1016/0166-9834(91)85055-z es_ES
dc.description.references Lee, J.-F., Chern, W.-S., Lee, M.-D., & Dong, T.-Y. (2009). Hydrogenation of carbon dioxide on iron catalysts doubly promoted with manganese and potassium. The Canadian Journal of Chemical Engineering, 70(3), 511-515. doi:10.1002/cjce.5450700314 es_ES
dc.description.references Pijolat, M., Perrichon, V., Primet, M., & Bussiere, P. (1982). Hydrocondensation of carbon dioxide over an iron-alumina catalyst: A three-step model. Journal of Molecular Catalysis, 17(2-3), 367-380. doi:10.1016/0304-5102(82)85048-7 es_ES
dc.description.references Guerrero-Ruiz, A., & Rodríguez-Ramos, I. (1985). Hydrogenation of CO2 on carbon-supported nickel and cobalt. Reaction Kinetics and Catalysis Letters, 29(1), 93-99. doi:10.1007/bf02067954 es_ES
dc.description.references Jahangiri, H., Bennett, J., Mahjoubi, P., Wilson, K., & Gu, S. (2014). A review of advanced catalyst development for Fischer–Tropsch synthesis of hydrocarbons from biomass derived syn-gas. Catal. Sci. Technol., 4(8), 2210-2229. doi:10.1039/c4cy00327f es_ES
dc.description.references Ramirez, A., Gevers, L., Bavykina, A., Ould-Chikh, S., & Gascon, J. (2018). Metal Organic Framework-Derived Iron Catalysts for the Direct Hydrogenation of CO2 to Short Chain Olefins. ACS Catalysis, 8(10), 9174-9182. doi:10.1021/acscatal.8b02892 es_ES
dc.description.references Anderson, R. B., Friedel, R. A., & Storch, H. H. (1951). Fischer‐Tropsch Reaction Mechanism Involving Stepwise Growth of Carbon Chain. The Journal of Chemical Physics, 19(3), 313-319. doi:10.1063/1.1748201 es_ES
dc.description.references Griboval-Constant, A., Butel, A., Ordomsky, V. V., Chernavskii, P. A., & Khodakov, A. Y. (2014). Cobalt and iron species in alumina supported bimetallic catalysts for Fischer–Tropsch reaction. Applied Catalysis A: General, 481, 116-126. doi:10.1016/j.apcata.2014.04.047 es_ES
dc.description.references Patzlaff, J., Liu, Y., Graffmann, C., & Gaube, J. (1999). Studies on product distributions of iron and cobalt catalyzed Fischer–Tropsch synthesis. Applied Catalysis A: General, 186(1-2), 109-119. doi:10.1016/s0926-860x(99)00167-2 es_ES
dc.description.references Patzlaff, J., Liu, Y., Graffmann, C., & Gaube, J. (2002). Interpretation and kinetic modeling of product distributions of cobalt catalyzed Fischer–Tropsch synthesis. Catalysis Today, 71(3-4), 381-394. doi:10.1016/s0920-5861(01)00465-5 es_ES
dc.description.references Torres Galvis, H. M., Bitter, J. H., Khare, C. B., Ruitenbeek, M., Dugulan, A. I., & de Jong, K. P. (2012). Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins. Science, 335(6070), 835-838. doi:10.1126/science.1215614 es_ES
dc.description.references Kim, H., Choi, D.-H., Nam, S.-S., Choi, M.-J., & Lee, K.-W. (1998). The selective synthesis of lower olefins(C2 - C4) by the CO2 hydrogenation over Iron catalysts promoted with Potassium and supported on ion exchanged(H, K) Zeolite-Y. Advances in Chemical Conversions for Mitigating Carbon Dioxide, Proceedings of the Fourth International Conference on Carbon Dioxide Utilization, 407-410. doi:10.1016/s0167-2991(98)80782-9 es_ES
dc.description.references Nam, S.-S., Kim, H., Kishan, G., Choi, M.-J., & Lee, K.-W. (1999). Catalytic conversion of carbon dioxide into hydrocarbons over iron supported on alkali ion-exchanged Y-zeolite catalysts. Applied Catalysis A: General, 179(1-2), 155-163. doi:10.1016/s0926-860x(98)00322-6 es_ES
dc.description.references Dokania, A., Ramirez, A., Bavykina, A., & Gascon, J. (2018). Heterogeneous Catalysis for the Valorization of CO2: Role of Bifunctional Processes in the Production of Chemicals. ACS Energy Letters, 4(1), 167-176. doi:10.1021/acsenergylett.8b01910 es_ES
dc.description.references Wei, J., Ge, Q., Yao, R., Wen, Z., Fang, C., Guo, L., … Sun, J. (2017). Directly converting CO2 into a gasoline fuel. Nature Communications, 8(1). doi:10.1038/ncomms15174 es_ES
dc.description.references Ramirez, A., Dutta Chowdhury, A., Dokania, A., Cnudde, P., Caglayan, M., Yarulina, I., … Gascon, J. (2019). Effect of Zeolite Topology and Reactor Configuration on the Direct Conversion of CO2 to Light Olefins and Aromatics. ACS Catalysis, 9(7), 6320-6334. doi:10.1021/acscatal.9b01466 es_ES
dc.description.references Mintova, S., Gilson, J.-P., & Valtchev, V. (2013). Advances in nanosized zeolites. Nanoscale, 5(15), 6693. doi:10.1039/c3nr01629c es_ES
dc.description.references Mintova, S., Jaber, M., & Valtchev, V. (2015). Nanosized microporous crystals: emerging applications. Chemical Society Reviews, 44(20), 7207-7233. doi:10.1039/c5cs00210a es_ES
dc.description.references Rimer, J. D., Kumar, M., Li, R., Lupulescu, A. I., & Oleksiak, M. D. (2014). Tailoring the physicochemical properties of zeolite catalysts. Catal. Sci. Technol., 4(11), 3762-3771. doi:10.1039/c4cy00858h es_ES
dc.description.references Díaz-Rey, M. R., Paris, C., Martínez-Franco, R., Moliner, M., Martínez, C., & Corma, A. (2017). Efficient Oligomerization of Pentene into Liquid Fuels on Nanocrystalline Beta Zeolites. ACS Catalysis, 7(9), 6170-6178. doi:10.1021/acscatal.7b00817 es_ES
dc.description.references Gallego, E. M., Paris, C., Díaz-Rey, M. R., Martínez-Armero, M. E., Martínez-Triguero, J., Martínez, C., … Corma, A. (2017). Simple organic structure directing agents for synthesizing nanocrystalline zeolites. Chemical Science, 8(12), 8138-8149. doi:10.1039/c7sc02858j es_ES
dc.description.references Gallego, E. M., Li, C., Paris, C., Martín, N., Martínez-Triguero, J., Boronat, M., … Corma, A. (2018). Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance. Chemistry - A European Journal, 24(55), 14631-14635. doi:10.1002/chem.201803637 es_ES
dc.description.references Martínez-Franco, R., Paris, C., Martínez-Armero, M. E., Martínez, C., Moliner, M., & Corma, A. (2016). High-silica nanocrystalline Beta zeolites: efficient synthesis and catalytic application. Chemical Science, 7(1), 102-108. doi:10.1039/c5sc03019f es_ES
dc.description.references Camblor, M. A., Corma, A., & Valencia, S. (1998). Characterization of nanocrystalline zeolite Beta. Microporous and Mesoporous Materials, 25(1-3), 59-74. doi:10.1016/s1387-1811(98)00172-3 es_ES
dc.description.references Boronat, M., & Corma, A. (2019). What Is Measured When Measuring Acidity in Zeolites with Probe Molecules? ACS Catalysis, 9(2), 1539-1548. doi:10.1021/acscatal.8b04317 es_ES
dc.description.references Ramirez, A., Ould‐Chikh, S., Gevers, L., Chowdhury, A. D., Abou‐Hamad, E., Aguilar‐Tapia, A., … Gascon, J. (2019). Tandem Conversion of CO 2 to Valuable Hydrocarbons in Highly Concentrated Potassium Iron Catalysts. ChemCatChem, 11(12), 2879-2886. doi:10.1002/cctc.201900762 es_ES
dc.description.references Arora, S. S., Shi, Z., & Bhan, A. (2019). Mechanistic Basis for Effects of High-Pressure H2 Cofeeds on Methanol-to-Hydrocarbons Catalysis over Zeolites. ACS Catalysis, 9(7), 6407-6414. doi:10.1021/acscatal.9b00969 es_ES
dc.description.references Dusselier, M., & Davis, M. E. (2018). Small-Pore Zeolites: Synthesis and Catalysis. Chemical Reviews, 118(11), 5265-5329. doi:10.1021/acs.chemrev.7b00738 es_ES
dc.description.references Moliner, M., Martínez, C., & Corma, A. (2013). Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis. Chemistry of Materials, 26(1), 246-258. doi:10.1021/cm4015095 es_ES
dc.description.references Tang, X., Zhou, H., Qian, W., Wang, D., Jin, Y., & Wei, F. (2008). High Selectivity Production of Propylene from n-Butene: Thermodynamic and Experimental Study Using a Shape Selective Zeolite Catalyst. Catalysis Letters, 125(3-4), 380-385. doi:10.1007/s10562-008-9564-8 es_ES
dc.description.references Weber, J. L., Dugulan, I., de Jongh, P. E., & de Jong, K. P. (2018). Bifunctional Catalysis for the Conversion of Synthesis Gas to Olefins and Aromatics. ChemCatChem, 10(5), 1107-1112. doi:10.1002/cctc.201701667 es_ES
dc.description.references Vermeiren, W., & Gilson, J.-P. (2009). Impact of Zeolites on the Petroleum and Petrochemical Industry. Topics in Catalysis, 52(9), 1131-1161. doi:10.1007/s11244-009-9271-8 es_ES
dc.description.references Tsai, T. (1999). Disproportionation and transalkylation of alkylbenzenes over zeolite catalysts. Applied Catalysis A: General, 181(2), 355-398. doi:10.1016/s0926-860x(98)00396-2 es_ES


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