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Selective Introduction of Acid Sites in Different Confined Positions in ZSM-5 and Its Catalytic Implications

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Selective Introduction of Acid Sites in Different Confined Positions in ZSM-5 and Its Catalytic Implications

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dc.contributor.author Li, Chengeng es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Miguel, Pablo J. es_ES
dc.contributor.author Dedecek, Jiri es_ES
dc.contributor.author Boronat Zaragoza, Mercedes es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-04-21T03:31:30Z
dc.date.available 2021-04-21T03:31:30Z
dc.date.issued 2018-08 es_ES
dc.identifier.issn 2155-5435 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165405
dc.description.abstract [EN] Controlling the location of acid sites in zeolites can have a great effect on catalysis. In this work we face the objective of directing the location of AI into the 10R channels of ZSM-5 by taking advantage of the structural preference of B to occupy certain positions at the channel intersections, as suggested by theoretical calculations. The synthesis of B-Al-ZSM-5 zeolites with variable Si/Al and Si/B ratios, followed by B removal in a postsynthesis treatment, produces ZSM-5 samples enriched in Al occupying positions at 10R channels. The location of the acid sites is determined on the basis of the product distribution of 1-hexene cracking as a test reaction. The higher selectivity to propene and lower C-4(=)/C-3(=) ratio in the samples synthesized with B and subsequently deboronated can be related to a larger concentration of acid sites in 10R channels, where monomolecular cracking occurs. Finally, several ZSM-5 samples have been tested in the methanol to propene reaction, and those synthesized through the B -assisted method show longer catalytic lifetime, higher propene yield, and lower yield of alkanes and aromatics. es_ES
dc.description.sponsorship This work was supported by the European Union through ERC-AdG-2014-671093 (SynCatMatch) and the Spanish Government-MINECO through "Severo Ochoa" (SEV-2016-0683) and CTQ2015-70126-R. The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization. Red Espanola de Supercomputacion (RES) and Centre de Calcul de la Universitat de Valencia are gratefully acknowledged for computational resources and technical support. C.L. acknowledges the China Scholarship Council (CSC) for a Ph.D. fellowship es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof ACS Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Zeolites es_ES
dc.subject DFT es_ES
dc.subject Al siting es_ES
dc.subject Boron ZSM-5 es_ES
dc.subject MTO es_ES
dc.subject Catalytic cracking es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Selective Introduction of Acid Sites in Different Confined Positions in ZSM-5 and Its Catalytic Implications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acscatal.8b02112 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Li, C.; Vidal Moya, JA.; Miguel, PJ.; Dedecek, J.; Boronat Zaragoza, M.; Corma Canós, A. (2018). Selective Introduction of Acid Sites in Different Confined Positions in ZSM-5 and Its Catalytic Implications. ACS Catalysis. 8(8):7688-7697. https://doi.org/10.1021/acscatal.8b02112 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acscatal.8b02112 es_ES
dc.description.upvformatpinicio 7688 es_ES
dc.description.upvformatpfin 7697 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 8 es_ES
dc.relation.pasarela S\385399 es_ES
dc.contributor.funder China Scholarship Council es_ES
dc.contributor.funder European Research Council es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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