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Molecular Oxygen Lignin Depolymerization: An Insight into the Stability of Phenolic Monomers

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Molecular Oxygen Lignin Depolymerization: An Insight into the Stability of Phenolic Monomers

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dc.contributor.author Mathieu, Yannick es_ES
dc.contributor.author Vidal, Juan D es_ES
dc.contributor.author Arribas Martínez, Lourdes es_ES
dc.contributor.author Abad Fernández, Nerea es_ES
dc.contributor.author Iborra Chornet, Sara es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2021-04-28T03:32:36Z
dc.date.available 2021-04-28T03:32:36Z
dc.date.issued 2020-09-07 es_ES
dc.identifier.issn 1864-5631 es_ES
dc.identifier.uri http://hdl.handle.net/10251/165733
dc.description This is the peer reviewed version of the following article: Y. Mathieu, J. D. Vidal, L. Arribas Martínez, N. Abad Fernández, S. Iborra, A. Corma, ChemSusChem 2020, 13, 4743, which has been published in final form at https://doi.org/10.1002/cssc.202001295. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] During oxidative depolymn. of lignin in aq. alk. medium using mol. oxygen as oxidant, the highly functionalized primary phenolic monomers are not stable products, owing to various not fully identified secondary reaction mechanisms. However, better understanding of the mechanisms responsible for the instability of the main part of the products of interest derived from lignin is of much interest. Evaluation of their individual reactivities under oxidative conditions should significantly help to find a better way to valorize the lignin polymer and to maximize the yields of target value-added products. Consequently, the main objective of this study is to assess the individual stabilities of some selected ligninbased phenolic compds., such as vanillin, vanillic acid, and acetovanillone, together with some other pure chem. compds. such as phenol and anisole to give an insight into the mechanisms responsible for the simultaneous formation and repolymn. of those products and the influence of the oxidn. conditions. Various complementary strategies of stabilization are proposed, discussed, and applied for the oxidative depolymn. reactions of a tech. lignin extd. from pinewood with a high content of b-O-4 interconnecting bonds to try to obtain enhanced yields of value-added products. es_ES
dc.description.sponsorship The authors thank Tecnicas Reunidas for material and financial support. We also acknowledge the Spanish Ministry of Science, Innovation, and Universities for funding through the "Severo Ochoa" Excellence Program (SEV 2016-0683) and the LIGNO-PRIZED project from the Spanish Centre for the Development of Industrial Technology (CDTI) in the framework of the Strategic Program of National Business Research Consortia (CIEN-2016). Special and kindly thanks are also given to Dr. Dalgi Sunith Barbosa Trillos and Dr. Jakob Mottweiler for their priceless help during the elaboration of the present work. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biomass valorization es_ES
dc.subject Depolymerization es_ES
dc.subject Lignin es_ES
dc.subject Oxidation es_ES
dc.subject Phenolic monomers es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Molecular Oxygen Lignin Depolymerization: An Insight into the Stability of Phenolic Monomers es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cssc.202001295 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Mathieu, Y.; Vidal, JD.; Arribas Martínez, L.; Abad Fernández, N.; Iborra Chornet, S.; Corma Canós, A. (2020). Molecular Oxygen Lignin Depolymerization: An Insight into the Stability of Phenolic Monomers. ChemSusChem. 13(17):4743-4758. https://doi.org/10.1002/cssc.202001295 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/cssc.202001295 es_ES
dc.description.upvformatpinicio 4743 es_ES
dc.description.upvformatpfin 4758 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 13 es_ES
dc.description.issue 17 es_ES
dc.identifier.pmid 32749077 es_ES
dc.relation.pasarela S\433143 es_ES
dc.contributor.funder Centro para el Desarrollo Tecnológico Industrial es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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