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Enhancing the stability and crystallinity of CsPbIBr2 through antisolvent engineering

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Enhancing the stability and crystallinity of CsPbIBr2 through antisolvent engineering

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dc.contributor.author Stewart, Alexander Wyn es_ES
dc.contributor.author Bouich, Amal es_ES
dc.contributor.author Marí, B. es_ES
dc.date.accessioned 2022-05-25T18:04:12Z
dc.date.available 2022-05-25T18:04:12Z
dc.date.issued 2021-12 es_ES
dc.identifier.issn 0022-2461 es_ES
dc.identifier.uri http://hdl.handle.net/10251/182924
dc.description.abstract [EN] All inorganic lead-based perovskites containing bromine-iodine alloys, such as CsPbIBr2, have arisen as one of the most attractive candidates for absorber layers in solar cells. That said, there remains a large gap when it comes to film and crystal quality between the inorganic and hybrid perovskites. In this work, antisolvent engineering is employed as a simple and reproducible method for improving CsPbIBr2 thin films. We found that both the antisolvent used and the conditions under which it was applied have a measurable impact on both the quality and stability of the final product. We arrived at this conclusion by characterising the samples using scanning electron microscopy, X-ray diffraction, UV-visible and photoluminescence measurements, as well as employing a novel system to quantify stability. Our findings, and the application of our novel method for quantifying stability, demonstrate the ability to significantly enhance CsPbIBr2 samples, produced via a static one-step spin coating method, by applying isopropanol 10 s after commencing the spin programme. The antisolvent quenched CsPbIBr2 films demonstrate both improved crystallinity and an extended lifespan es_ES
dc.description.sponsorship Open Access funding provided thanks to the CRUE-CSIC agreement with Springer Nature. This study was funded by the Generalitat Valenciana and the European Union (ACIF/2020/286) and the Ministerio de Economía y Competitividad (Grant Number PID2019-107137RB-C21) es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Enhancing the stability and crystallinity of CsPbIBr2 through antisolvent engineering es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-021-06552-3 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107137RB-C21/ES/MEJORANDO LA PRODUCCION DE ENERGIA SOLAR CON PEROVSKITAS INORGANICAS.SINTESIS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//ACIF%2F2020%2F286//AYUDA PREDOCTORAL GVA-STEWART. PROYECTO: PEROVSKITAS HIBRIDAS PARA APLICACIONES FOTOVOLTAICAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Diseño para la Fabricación y Producción Automatizada - Institut de Disseny per a la Fabricació i Producció Automatitzada es_ES
dc.description.bibliographicCitation Stewart, AW.; Bouich, A.; Marí, B. (2021). Enhancing the stability and crystallinity of CsPbIBr2 through antisolvent engineering. Journal of Materials Science. 56(36):20071-20086. https://doi.org/10.1007/s10853-021-06552-3 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s10853-021-06552-3 es_ES
dc.description.upvformatpinicio 20071 es_ES
dc.description.upvformatpfin 20086 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 56 es_ES
dc.description.issue 36 es_ES
dc.relation.pasarela S\446924 es_ES
dc.contributor.funder GENERALITAT VALENCIANA es_ES
dc.contributor.funder AGENCIA ESTATAL DE INVESTIGACION es_ES
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