Mostrar el registro sencillo del ítem
dc.contributor.author | Rojas-Buzo, Sergio | es_ES |
dc.contributor.author | Bohigues, Benjamin | es_ES |
dc.contributor.author | Lopes, Christian W. | es_ES |
dc.contributor.author | Meira, Débora M. | es_ES |
dc.contributor.author | Boronat Zaragoza, Mercedes | es_ES |
dc.contributor.author | Moliner Marin, Manuel | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2022-07-14T18:04:12Z | |
dc.date.available | 2022-07-14T18:04:12Z | |
dc.date.issued | 2021-08-07 | es_ES |
dc.identifier.issn | 2041-6520 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/184210 | |
dc.description.abstract | [EN] The Lewis/Bronsted catalytic properties of the Metal-Organic Framework (MOF) nodes can be tuned by simply controlling the solvent employed in the synthetic procedure. In this work, we demonstrate that Hf-MOF-808 can be prepared from a material with a higher amount of Bronsted acid sites, via modulated hydrothermal synthesis, to a material with a higher proportion of unsaturated Hf Lewis acid sites, via modulated solvothermal synthesis. The Lewis/Bronsted acid properties of the resultant metallic clusters have been studied by different characterization techniques, including XAS, FTIR and NMR spectroscopies, combined with a DFT study. The different nature of the Hf-MOF-808 materials allows their application as selective catalysts in different target reactions requiring Lewis, Bronsted or Lewis-Bronsted acid pairs. | es_ES |
dc.description.sponsorship | This work has been supported by the Spanish Government through the "Severo Ochoa" (SEV-2016-0683, MINECO), MAT2017-82288-C2-1-P (AEI/FEDER, UE) and RTI2018-101033-B-I00 (MCIU/AEI/FEDER, UE). J. M. Salas is acknowledged for his contribution to CD<INF>3</INF>CN-FTIR experiments. C. W. L. thanks the PRH 50.1 - ANP/FINEP Human Resources Program for the Visiting Researcher Fellowship. This research used resources of the Advanced Photon Source, a user facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory, and was supported by the U.S. DOE under Contract No. DE-AC02-06CH11357 and by the Canadian Light Source and its funding partners. The Electron Microscopy Service of the UPV is also acknowledged for their help in sample characterization. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Chemical Science | es_ES |
dc.rights | Reconocimiento - No comercial (by-nc) | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Tailoring Lewis/Bronsted acid properties of MOF nodes via hydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/d1sc02833b | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/DOE//DE-AC02-06CH11357/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD//SEV-2016-0683//Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Rojas-Buzo, S.; Bohigues, B.; Lopes, CW.; Meira, DM.; Boronat Zaragoza, M.; Moliner Marin, M.; Corma Canós, A. (2021). Tailoring Lewis/Bronsted acid properties of MOF nodes via hydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications. Chemical Science. 12(29):10106-10115. https://doi.org/10.1039/d1sc02833b | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/d1sc02833b | es_ES |
dc.description.upvformatpinicio | 10106 | es_ES |
dc.description.upvformatpfin | 10115 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 12 | es_ES |
dc.description.issue | 29 | es_ES |
dc.identifier.pmid | 34349973 | es_ES |
dc.identifier.pmcid | PMC8317639 | es_ES |
dc.relation.pasarela | S\456197 | es_ES |
dc.contributor.funder | U.S. Department of Energy | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.contributor.funder | Ministerio Ciencia, Innovación y Universidades | es_ES |
dc.contributor.funder | MINISTERIO DE ECONOMÍA, INDUSTRIA Y COMPETITIVIDAD | es_ES |