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dc.contributor.author | Herrera-Luna, Jorge Carlos | es_ES |
dc.contributor.author | Díaz Díaz, David | es_ES |
dc.contributor.author | Abramov, Alex | es_ES |
dc.contributor.author | Encinas Perea, Susana | es_ES |
dc.contributor.author | Jiménez Molero, María Consuelo | es_ES |
dc.contributor.author | Pérez-Ruiz, Raúl | es_ES |
dc.date.accessioned | 2022-11-18T19:01:23Z | |
dc.date.available | 2022-11-18T19:01:23Z | |
dc.date.issued | 2021-03-19 | es_ES |
dc.identifier.issn | 1523-7060 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/189905 | |
dc.description.abstract | [EN] Heteroarene boronate esters constitute valuable intermediates in modern organic synthesis. As building blocks, they can be further applied to the synthesis of new materials, since they can be easily transformed into any other functional group. Efforts toward novel and efficient strategies for their preparation are clearly desirable. Here, we have achieved the borylation of commercially available heteroarene halides under very mild conditions in an easy-to-use gel nanoreactor. Its use of visible light as the energy source at room temperature in photocatalyst-free and aerobic conditions makes this protocol very attractive. The gel network provides an adequate stabilizing microenvironment to support wide substrate scope, including furan, thiophene, selenophene, and pyrrole boronate esters. | es_ES |
dc.description.sponsorship | Financial support from the Generalitat Valenciana (CIDEGENT/2018/044) and the Spanish Ministry of Science and Innovation (PID2019-105391GB-C21, PID2019-105391GBC22, BEAGAL18/00166, and BES-2017-080215) is gratefully acknowledged. We thank the Electron Microscopy Service from the UPV and Prof. Julia Perez-Prieto for spectroscopy facilities. D.D.D. also thanks NANOtec, INTech, Cabildo de Tenerife, and ULL for laboratory facilities. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Organic Letters | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Aerobic gel | es_ES |
dc.subject | Nanoreactor | es_ES |
dc.subject | Visible light | es_ES |
dc.subject | Borylation | es_ES |
dc.subject | Heteroarenes | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Aerobic Visible-Light-Driven Borylation of Heteroarenes in a Gel Nanoreactor | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/acs.orglett.1c00451 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105391GB-C21/ES/DESARROLLO DE FORMULACIONES A BASE DE GEL PARA CATALISIS REDOX BASADA EN ANIQUILACION TRIPLETE-TRIPLETE USANDO LUZ VISIBLE/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GENERALITAT VALENCIANA//CIDEGENT%2F2018%2F044//AYUDA CIDEGENT CONTRATACION RAUL PEREZ RUIZ/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-105391GB-C22/ES/DESARROLLO DE NUEVOS SISTEMAS DE CONVERSION BIFOTONICA A MAYOR FRECUENCIA BASADOS EN ANIQUILACION TRIPLETE-TRIPLETE PARA FOTOCATALISIS REDOX CON LUZ VISIBLE/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//BES-2017-080215//AYUDA PARA CONTRATOS PREDOCTORALES PARA LA FORMACION DE DOCTORES 2017-HERRERA LUNA. PROYECTO: CONTROL SUPRAMOLECULAR DE LA FOTORREACTIVIDAD EN MEDIOS MICROHETEROGENOS BASADOS EN AMINOACIDOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MCIU//BEAGAL18%2F00166/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Herrera-Luna, JC.; Díaz Díaz, D.; Abramov, A.; Encinas Perea, S.; Jiménez Molero, MC.; Pérez-Ruiz, R. (2021). Aerobic Visible-Light-Driven Borylation of Heteroarenes in a Gel Nanoreactor. Organic Letters. 23(6):2320-2325. https://doi.org/10.1021/acs.orglett.1c00451 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acs.orglett.1c00451 | es_ES |
dc.description.upvformatpinicio | 2320 | es_ES |
dc.description.upvformatpfin | 2325 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 23 | es_ES |
dc.description.issue | 6 | es_ES |
dc.identifier.pmid | 33650873 | es_ES |
dc.identifier.pmcid | PMC8719754 | es_ES |
dc.relation.pasarela | S\429956 | es_ES |
dc.contributor.funder | GENERALITAT VALENCIANA | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades | es_ES |