Ramirez Hoyos, P.; Cervera Montesinos, J.; Ali, M.; Nasir, S.; Ensinger, W.; Mafe, S. (2020). Impact of Surface Charge Directionality on Membrane Potential in
Multi-ionic Systems. The Journal of Physical Chemistry Letters. 11(7):2530-2534. https://doi.org/10.1021/acs.jpclett.0c00554
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/193522
Título:
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Impact of Surface Charge Directionality on Membrane Potential in
Multi-ionic Systems
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Autor:
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Ramirez Hoyos, Patricio
Cervera Montesinos, Javier
Ali, Mubarak
Nasir, Saima
Ensinger, Wolfgang
Mafe, Salvador
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Entidad UPV:
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Universitat Politècnica de València. Escuela Técnica Superior de Arquitectura - Escola Tècnica Superior d'Arquitectura
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Fecha difusión:
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Resumen:
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[EN] The membrane potential (V-mem), defined as the electric potential difference across a membrane flanked by two different salt solutions, is central to electrochemical energy harvesting and conversion. Also, V-mem and ...[+]
[EN] The membrane potential (V-mem), defined as the electric potential difference across a membrane flanked by two different salt solutions, is central to electrochemical energy harvesting and conversion. Also, V-mem and the ionic concentrations that establish it are important to biophysical chemistry because they regulate crucial cell processes. We study experimentally and theoretically the salt dependence of V-mem in single conical nanopores for the case of multi-ionic systems of different ionic charge numbers. The major advances of this work are (i) to measure Vmem using a series of ions (Na+, K+, Ca2+, Cl-, and SO42-) that are of interest to both energy conversion and cell biochemistry, (ii) to describe the physicochemical effects resulting from the nanostructure asymmetry, (iii) to develop a theoretical model for multi-ionic systems, and (iv) to quantify the contributions of the liquid junction potentials established in the salt bridges to the total cell membrane potential.
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Derechos de uso:
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Reserva de todos los derechos
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Fuente:
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The Journal of Physical Chemistry Letters. (issn:
1948-7185
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DOI:
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10.1021/acs.jpclett.0c00554
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Editorial:
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American Chemical Society
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Versión del editor:
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https://doi.org/10.1021/acs.jpclett.0c00554
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Código del Proyecto:
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-097359-B-I00/ES/NANOESTRUCTURAS POROSAS DE INSPIRACION BIOLOGICA: ANALISIS Y CONTROL DE SEÑALES ELECTRICAS/
info:eu-repo/grantAgreement/GSI//FAIR Phase/
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Agradecimientos:
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M.A., S.N., and W.E. gratefully acknowledge the financial support from the Hessen State Ministry of Higher Education, Research and the Arts (Germany), LOEWE Project iNAPO. The heavy ion irradiation of polymer membranes are ...[+]
M.A., S.N., and W.E. gratefully acknowledge the financial support from the Hessen State Ministry of Higher Education, Research and the Arts (Germany), LOEWE Project iNAPO. The heavy ion irradiation of polymer membranes are based on a UMAT experiment, which was performed at the X0-beamline of the UNILAC at the GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany) in the frame of FAIR Phase-0. P.R., J.C., and S.M. acknowledge the funding from the Ministerio de Economia y Competitividad and the European Regional Development Funds (FEDER), Project PGC2018-097359-B-I00.
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Tipo:
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Artículo
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