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dc.contributor.author | De Arriba-Mateos, Agustín | es_ES |
dc.contributor.author | Solsona, Benjamin | es_ES |
dc.contributor.author | Garcia-Gonzalez, Ester | es_ES |
dc.contributor.author | Concepción Heydorn, Patricia | es_ES |
dc.contributor.author | López Nieto, José Manuel | es_ES |
dc.date.accessioned | 2023-05-24T18:02:24Z | |
dc.date.available | 2023-05-24T18:02:24Z | |
dc.date.issued | 2022-08-05 | es_ES |
dc.identifier.issn | 0926-860X | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/193582 | |
dc.description.abstract | [EN] Undoped and Te-doped MoV-Oxide (M1 phase) catalysts have been prepared hydrothermally (Te/Mo ratio in the synthesis gel from 0 to 0.17; and heat-treated at 400 or 600ºC in N2 atmosphere), characterized by several physicochemical techniques and tested in the oxidative dehydrogenation (ODH) of ethane. The morphology and microporosity of the catalysts, the nature of V-species on the catalyst surface and the catalytic performance strongly depend on the composition and the heat-treatment temperature. When calcined at 400ºC, the selectivity to ethylene decreases when the amount of tellurium increases, whereas when heat treated at 600ºC, the selectivity to ethylene increases when the Te-loading increases. These trends have been explained on the basis of the good correlation between selectivity to ethylene and the concentration of V4+ species on the surface of catalysts, in which the most selective catalyst is that prepared with a Te/Mo ratio of 0.17 and heat-treated at 600ºC. | es_ES |
dc.description.sponsorship | The authors would like to thank the Spanish Ministry of Economy and Competitiveness for funding the projects (MINECO/FEDER) : CRTl2018-099668-B-C21, PID2019-106662RBC44, MAT2017-84118- C2-1-R and SEV-2016-0683. A.A. acknowledges Severo Ochoa Excellence Program for his fellowship (BES-2017-080329) . Authors would also like to acknowledge the "A -Team" of the ITQ (Dr. Miguel Palomino, Dr. Susana Valencia and Prof. Fernando Rey) for their assistance in the performance of the adsorption experiments. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Applied Catalysis A General | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Ethylene | es_ES |
dc.subject | Ethane ODH | es_ES |
dc.subject | Mo-V-O oxide | es_ES |
dc.subject | M1 phase | es_ES |
dc.subject | Tellurium | es_ES |
dc.title | Te-doped MoV-Oxide (M1 phase) for ethane ODH. The role of tellurium on morphology, thermal stability and catalytic behaviour | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.apcata.2022.118780 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84118-C2-1-R/ES/VALORIZACION DE RECURSOS NATURALES COMO NUEVOS MATERIALES AVANZADOS :APLICACIONES CATALITICAS Y ELECTROQUIMICAS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/Comisión Interministerial de Ciencia y Tecnología//RTI2018-099668-B-C21//VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106662RB-C44/ES/MATERIALES CON ALTAS PRESTACIONES PARA BATERIAS MAS SEGURAS, Y PILAS DE COMBUSTIBLES DE OXIDO SOLIDO SIMETRICAS MAS ECONOMICAS: DESARROLLO DE MATERIALES Y PROTOTIPOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//BES-2017-080329/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.description.bibliographicCitation | De Arriba-Mateos, A.; Solsona, B.; Garcia-Gonzalez, E.; Concepción Heydorn, P.; López Nieto, JM. (2022). Te-doped MoV-Oxide (M1 phase) for ethane ODH. The role of tellurium on morphology, thermal stability and catalytic behaviour. Applied Catalysis A General. 643:1-13. https://doi.org/10.1016/j.apcata.2022.118780 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.apcata.2022.118780 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 13 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 643 | es_ES |
dc.relation.pasarela | S\472930 | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Comisión Interministerial de Ciencia y Tecnología | es_ES |
dc.contributor.funder | Ministerio de Economía, Industria y Competitividad | es_ES |
dc.contributor.funder | Universitat Politècnica de València | |
dc.subject.ods | 12.- Garantizar las pautas de consumo y de producción sostenibles | es_ES |