Viciano-Chumillas, M.; Liu, X.; Leyva Perez, A.; Armentano, D.; Ferrando-Soria, J.; Pardo, E. (2022). Mixed component metal-organic frameworks: Heterogeneity and
complexity at the service of application performances. Coordination Chemistry Reviews. 451:1-57. https://doi.org/10.1016/j.ccr.2021.214273
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/202748
Título:
|
Mixed component metal-organic frameworks: Heterogeneity and
complexity at the service of application performances
|
Autor:
|
Viciano-Chumillas, Marta
Liu, Xiangyu
Leyva Perez, Antonio
Armentano, Donatella
Ferrando-Soria, Jesús
Pardo, Emilio
|
Entidad UPV:
|
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
|
Fecha difusión:
|
|
Resumen:
|
[EN] The synthesis of mixed-component metal-organic frameworks (MOFs) -including multivariate MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and metals MOFs- is becoming a very active research ...[+]
[EN] The synthesis of mixed-component metal-organic frameworks (MOFs) -including multivariate MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and metals MOFs- is becoming a very active research field. This is mainly based on the unique possibilities these materials offer to incorporate multiple functionalities and in how this heterogenity and complexity is translated in unexpected properties, which are not just the sum of each component. This review critically encompasses the progress made in this field, covering the synthetic approaches, and specially focusing on the current reported applications -such as gas storage and separation, catalysis, luminescence, conductivity, biological ones and water remediation. It also raises, as a perspective, some of the challenges the field has to overcome to reach their full-potential, and through two applications -(bio)enzymatic catalysis and synthesis of heterometallic subnanometric clusters and nanoparticles-, as exemplary cases, present some promising ways to take advantage of the intrinsic properties of mixed-components MOFs to make a breakthrough on the respective fields of application.
[-]
|
Palabras clave:
|
Mixed-component metal-organic frameworks
,
Multivariate MOFs
,
Multicomponent MOFs
,
Mixed-metals MOFs
,
Mixed-ligands and metals MOFs
|
Derechos de uso:
|
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
|
Fuente:
|
Coordination Chemistry Reviews. (issn:
0010-8545
)
|
DOI:
|
10.1016/j.ccr.2021.214273
|
Editorial:
|
Elsevier
|
Versión del editor:
|
https://doi.org/10.1016/j.ccr.2021.214273
|
Código del Proyecto:
|
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-86735-P/ES/CATALISIS CON ATOMOS METALICOS AISLADOS Y CLUSTERES ULTRAPEQUEÑOS BIEN DEFINIDOS, SIN LIGANDOS Y CONFINADOS/
...[+]
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-86735-P/ES/CATALISIS CON ATOMOS METALICOS AISLADOS Y CLUSTERES ULTRAPEQUEÑOS BIEN DEFINIDOS, SIN LIGANDOS Y CONFINADOS/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104778GB-I00/ES/DESARROLLO DE POLIMEROS DE COORDINACION POROSOS FUNCIONALES CON APLICACIONES TECNOLOGICAS Y MEDIOAMBIENTALES/
info:eu-repo/grantAgreement/EC/H2020/814804/EU
info:eu-repo/grantAgreement/NSFC//2020AAC02005/
info:eu-repo/grantAgreement/GVA//SEJI%2F2020%2F034/
info:eu-repo/grantAgreement/MCIU//RTC-2017-6331-5//NUEVA SINTESIS DEL OLIGOMERO CLAVE EN TINTAS DIGITALES/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
info:eu-repo/grantAgreement/Fundació Bancària Caixa d'Estalvis i Pensions de Barcelona//100010434/
info:eu-repo/grantAgreement/Fundació Bancària Caixa d'Estalvis i Pensions de Barcelona//LCF%2FBQ%2FPR19%2F11700011/
info:eu-repo/grantAgreement/Fondazione Cariplo//2019-2090/
info:eu-repo/grantAgreement/MICINN//CEX2019-000919-M/
[-]
|
Agradecimientos:
|
This work was supported by the Ministero dell'Istruzione, dell'Universita e della Ricerca (Italy), the Natural Science Foundation of Ningxia Province (China) (2020AAC02005) and the MINECO (Spain) (Projects PID2019-104778GB-I00, ...[+]
This work was supported by the Ministero dell'Istruzione, dell'Universita e della Ricerca (Italy), the Natural Science Foundation of Ningxia Province (China) (2020AAC02005) and the MINECO (Spain) (Projects PID2019-104778GB-I00, CTQ 2017-86735-P, RTC-2017-6331-5, Severo Ochoa program SEV-2016-0683 and Excellence Unit ``Maria de Maeztu"CEX2019-000919-M). D.A. acknowledges the financial support of the Fondazione CARIPLO/''Economia Circolare: ricerca per un futuro sostenibile" 2019, Project code: 2019-2090, MOCA. Thanks are also extended to the ''2019 Post-doctoral Junior Leader-Retaining Fellowship, la Caixa Foundation (ID100010434 and fellowship code LCF/BQ/PR19/11700011)", the ''Ramon y Cajal Programme" and ''Subvenciones concedidas a la excelencia cientifica de juniors investigadores, SEJI/2020/034" (J. F.-S.). E.P. acknowledges the financial support of the European Research Council under the European Union's Horizon 2020 research and innovation programme/ERC Grant Agreement No 814804, MOF-reactors.
[-]
|
Tipo:
|
Artículo
|