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dc.contributor.author | Salcedo-Abraira, Pablo | es_ES |
dc.contributor.author | Serrano Nieto, Rubén | es_ES |
dc.contributor.author | Biglione, Catalina | es_ES |
dc.contributor.author | Cabrero-Antonino, Maria | es_ES |
dc.contributor.author | Vilela, Sérgio M.F. | es_ES |
dc.contributor.author | Babaryk, Artem A. | es_ES |
dc.contributor.author | Tilve-Martínez, David | es_ES |
dc.contributor.author | Rodriguez-Diéguez, Antonio | es_ES |
dc.contributor.author | Navalón Oltra, Sergio | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Horcajada, Patricia | es_ES |
dc.date.accessioned | 2024-04-23T18:06:28Z | |
dc.date.available | 2024-04-23T18:06:28Z | |
dc.date.issued | 2023-06-01 | es_ES |
dc.identifier.issn | 0897-4756 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/203711 | |
dc.description.abstract | [EN] Two novel three-dimensional metal-organic frameworks(MOFs)based on the photoactive pyrene tetraphosphonate ligand and copper(denoted as IEF-8 and IEF-9) have been hydrothermally synthesizedand fully characterized (XRD, FTIR, TGA, SEM, XPS, etc.). Their crystalstructures were unveiled by single-crystal X-ray diffraction. Remarkably,these materials exhibit coordinatively unsaturated copper (II) sites,free -PO3H2 and -PO3H acidic groups, and good thermal and chemical stability. Further,their optoelectronic characterization evidenced a photoresponse suitablefor photocatalysis. In this sense, the photocatalytic activity ofpyrene phosphonate MOFs was evaluated for the first time for the challenginghydrogen evolution reaction. In particular, IEF-8 exhibited a catalyticefficiency higher than that of the benchmarked Ti carboxylate photocatalystMIL-125-(Ti)-NH2, producing 1800 mu mol center dot g(-1) after 22 h under UV-vis irradiation in theabsence of any co-catalyst. Furthermore, this material presented goodreusability (at least up to 4 cycles), preserving its activity andstructural integrity. | es_ES |
dc.description.sponsorship | The authors acknowledge the Maria de Maeztu IMDEA Energy Institute, the M-ERA-NET C-MOF-cell project, the Retos Investigacion MOFSEIDON project (PID2019-104228RB-I00 funded by MCIN/AEI/10.13039/501100011033 and by the European Union, MICIU-AEI/FEDER, UE), and the H2-MOF project (TED2021-132092B-C21 funded by MCIN/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR). They thank "Comunidad de Madrid" and European Regional Development Fund-FEDER 2014-2020-OE REACT-UE 1for their financial support to the VIRMOF-CM project associated to R & D projects in response to COVID-19. S.N. thanks the support of grant PID2021-123856OBI00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Chemistry of Materials | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Two Cu-Based Phosphonate Metal-Organic Frameworks as Efficient Water-Splitting Photocatalysts | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/acs.chemmater.3c00054 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104228RB-I00/ES/SEPARACION Y (FOTO)DEGRADACION COMBINADA DE CONTAMINANTES EN AGUA UTILIZANDO DISPOSITIVOS BASADOS EN REDES METAL-ORGANICAS POROSAS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123856OB-I00/ES/FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI//TED2021-132092B-C21//H2-MOF/ | es_ES |
dc.rights.accessRights | Embargado | es_ES |
dc.date.embargoEndDate | 2024-06-01 | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Salcedo-Abraira, P.; Serrano Nieto, R.; Biglione, C.; Cabrero-Antonino, M.; Vilela, SM.; Babaryk, AA.; Tilve-Martínez, D.... (2023). Two Cu-Based Phosphonate Metal-Organic Frameworks as Efficient Water-Splitting Photocatalysts. Chemistry of Materials. 35(11):4211-4219. https://doi.org/10.1021/acs.chemmater.3c00054 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acs.chemmater.3c00054 | es_ES |
dc.description.upvformatpinicio | 4211 | es_ES |
dc.description.upvformatpfin | 4219 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 35 | es_ES |
dc.description.issue | 11 | es_ES |
dc.relation.pasarela | S\510680 | es_ES |
dc.contributor.funder | Comunidad de Madrid | es_ES |
dc.contributor.funder | AGENCIA ESTATAL DE INVESTIGACION | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | European Regional Development Fund | es_ES |