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Iron-Catalysed Markovnikov Hydrothiolation of Styrenes

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Iron-Catalysed Markovnikov Hydrothiolation of Styrenes

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dc.contributor.author Cabrero Antonino, Jose Ramón es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2013-06-24T12:05:08Z
dc.date.issued 2012-02-23
dc.identifier.issn 1615-4150
dc.identifier.uri http://hdl.handle.net/10251/30028
dc.description.abstract The bis(triflimide)iron(III) salt catalyzes the hydrothiolation of styrenes in a Markovnikov fashion with good selectivities and high yields. After isolation, different benzylic thioethers are obtained. This iron(III) catalyst is unique in terms of regioselectivity and represents a sustainable and economic alternative to those processes based on stoichiometric reagents. es_ES
dc.description.sponsorship The work have been supported by Consolider-Ingenio 2010 (proyecto MULTICAT), and PROMETEO from Generalitat Valenciana. J.R.C.-A. thanks MCIINN for the provision of a doctoral grant. A.L.-P. thanks ITQ for financial support. We thank Dr. M. Domine for the HR-MS measurements. en_EN
dc.language Inglés es_ES
dc.publisher Wiley-VCH Verlag es_ES
dc.relation.ispartof Advanced Synthesis and Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Benzylic thioethers es_ES
dc.subject Bis(triflimide)- iron(III) es_ES
dc.subject Hydrothiolation es_ES
dc.subject Iron catalysis es_ES
dc.subject Markovnikov addition es_ES
dc.subject Styrenes es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Iron-Catalysed Markovnikov Hydrothiolation of Styrenes es_ES
dc.type Artículo es_ES
dc.embargo.lift 10000-01-01
dc.embargo.terms forever es_ES
dc.identifier.doi 10.1002/adsc.201100731
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Cabrero Antonino, JR.; Leyva Perez, A.; Corma Canós, A. (2012). Iron-Catalysed Markovnikov Hydrothiolation of Styrenes. Advanced Synthesis and Catalysis. 354:678-687. doi:10.1002/adsc.201100731 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://onlinelibrary.wiley.com/doi/10.1002/adsc.201100731/pdf es_ES
dc.description.upvformatpinicio 678 es_ES
dc.description.upvformatpfin 687 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 354 es_ES
dc.relation.senia 220599
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Instituto de Tecnología Química UPV-CSIC es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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