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Removal of 8-quinolinecarboxylic acid pesticide from aqueous solution by adsorption on activated montmorillonites

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Removal of 8-quinolinecarboxylic acid pesticide from aqueous solution by adsorption on activated montmorillonites

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Nombre: M. Mekhloufi;A. ...
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dc.contributor.author Mekhloufi, M. es_ES
dc.contributor.author Zehhaf, A. es_ES
dc.contributor.author Benyoucef, Abdelghani es_ES
dc.contributor.author Quijada Tomás, Cesar es_ES
dc.contributor.author Morallon, Emilia es_ES
dc.date.accessioned 2015-12-30T08:31:01Z
dc.date.available 2015-12-30T08:31:01Z
dc.date.issued 2013-12
dc.identifier.issn 0167-6369
dc.identifier.uri http://hdl.handle.net/10251/59285
dc.description.abstract Sodium montmorillonite (Na-M), acidic montmorillonite (H-M), and organo-acidic montmorillonite (Org-H-M) were applied to remove the herbicide 8-quinolinecarboxylic acid (8-QCA). The montmorillonites containing adsorbed 8-QCA were investigated by transmission electron microscopy, FT-IR spectroscopy, X-ray diffraction analysis, X-ray fluorescence thermogravimetric analysis, and physical adsorption of gases. Experiments showed that the amount of adsorbed 8-QCA increased at lower pH, reaching a maximum at pH 2. The adsorption kinetics was found to follow the pseudo-second-order kinetic model. The Langmuir model provided the best correlation of experimental data for adsorption equilibria. The adsorption of 8-QCA decreased in the order Org-H-M > H-M > Na-M. Isotherms were also used to obtain the thermodynamic parameters. The negative values of Delta G indicated the spontaneous nature of the adsorption process. es_ES
dc.description.sponsorship This work was supported by the National Agency for the Development of University Research (CRSTRA) and the Directorate General of Scientific Research and Technological Development of Algeria. The Ministerio de Economia y Competitividad (MAT2010-15273 project) and FEDER are also acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Environmental Monitoring and Assessment es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Adsorption isotherms es_ES
dc.subject 8-Quinolinecarboxylic acid es_ES
dc.subject Activated montmorillonite es_ES
dc.subject Kinetics es_ES
dc.subject Thermodynamic data es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title Removal of 8-quinolinecarboxylic acid pesticide from aqueous solution by adsorption on activated montmorillonites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10661-013-3338-5
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2010-15273/ES/ELECTRODOS NANOESTRUCTURADOS PARA APLICACIONES EN SENSORES ELECTROQUIMICOS Y SUPERCONDENSADORES/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Mekhloufi, M.; Zehhaf, A.; Benyoucef, A.; Quijada Tomás, C.; Morallon, E. (2013). Removal of 8-quinolinecarboxylic acid pesticide from aqueous solution by adsorption on activated montmorillonites. Environmental Monitoring and Assessment. 185(12):10365-10375. https://doi.org/10.1007/s10661-013-3338-5 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10661-013-3338-5 es_ES
dc.description.upvformatpinicio 10365 es_ES
dc.description.upvformatpfin 10375 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 185 es_ES
dc.description.issue 12 es_ES
dc.relation.senia 252011 es_ES
dc.identifier.eissn 1573-2959
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder Centre de Recherche Scientifique et Technique sur les Régions Arides, Argelia es_ES
dc.contributor.funder Direction Générale de la Recherche Scientifique et du Développement Technologique, Argelia es_ES
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