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dc.contributor.author | Borrás García, Esther Mª | es_ES |
dc.contributor.author | Ródenas, M. | es_ES |
dc.contributor.author | Dieguez, J.J. | es_ES |
dc.contributor.author | Pérez-García, M.L. | es_ES |
dc.contributor.author | Lomba, R. | es_ES |
dc.contributor.author | Lavin, J. | es_ES |
dc.contributor.author | Tortajada-Genaro, Luis Antonio | es_ES |
dc.date.accessioned | 2016-07-01T10:54:47Z | |
dc.date.available | 2016-07-01T10:54:47Z | |
dc.date.issued | 2012-03 | |
dc.identifier.issn | 0026-265X | |
dc.identifier.uri | http://hdl.handle.net/10251/66919 | |
dc.description.abstract | [EN] Carbon disulfide (CS2), a relevant reduced sulfur compound in air, is well-known for its malodor and its significant effect on global atmospheric chemistry. Therefore, a reliable method for determining CS2 in atmospheric samples has been developed based on solid-phase sampling and gas chromatography-mass spectrometry (GC-MS). Two types of solid-phase sampling supports (Orbo-32 and SKC) and the elution with organic solvents - hexane and toluene - were evaluated for low-volume outdoor sampling. Recovery studies and the standard addition method were carried out to demonstrate the proper determination of CS2 in the absence of the influence of interferences such as ozone, hydrogen sulfide or water - important atmospheric pollutants. The proposed methodology was validated by performing experiments in a high-volume smog chamber and by comparison with two reference optical methods, Fourier Transform Infrared (FTIR) and Differential Optical Absorption Spectroscopy (DOAS) installed in these facilities. Satisfactory analytical parameters were reported: fast analysis, a correct repeatability of 6±1% and reproducibility of 14±3%, and low detection limits of 0.3-0.9pgm-3. Finally, the method was successfully applied to industrial samples near a pulp factory area, where a high correlation between industrial emissions and reported carbon disulfide concentrations were observed. © 2011 Elsevier B.V. | es_ES |
dc.description.sponsorship | The research leading to these results received funding from the Centro de Investigacion del Medio Ambiente (CIMA), Consejeria de Medio Ambiente, Gobierno de Cantabria. The Instituto Universitario CEAM-UMH is partly supported by Generalitat Valenciana, Fundacion Bancaja, and the projects GRACCIE (Consolider-Ingenio 2010) and FEEDBACKS (Prometeo - Generalitat Valenciana). We also acknowledged the European Community's Seventh Framework Program under the grant agreement no. 228335 (Eurochamp2), the Spanish Ministry of Science and Innovation, through INNPLANTA project: PCT-440000-2010-003 and the EUPHORE staff for their support in the chamber experiments. The authors also thank J.T.B. for his contribution. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Microchemical Journal | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Atmospheric samples | es_ES |
dc.subject | Carbon disulfide | es_ES |
dc.subject | Gas chromatography-mass spectrometry | es_ES |
dc.subject | Pulp emissions | es_ES |
dc.subject | Solid-phase sampling | es_ES |
dc.subject.classification | QUIMICA ANALITICA | es_ES |
dc.title | Development of a gas chromatography - mass spectrometry method for the determination of carbon disulfide in the atmosphere | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.microc.2011.10.002 | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/228335/EU/Integration of European Simulation Chambers for Investigating Atmospheric Processes - Part 2/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//PCT-440000-2010-003/ES/ADQUISICION Y MEJORA DE TÉCNICAS INTRUMENTALES PARA LA INVESTIGACIÓN DE LOS PROCESOS QUÍMICOS ATMOSFÉRICOS EN CÁMARAS DE SIMULACIÓN/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Borrás García, EM.; Ródenas, M.; Dieguez, J.; Pérez-García, M.; Lomba, R.; Lavin, J.; Tortajada-Genaro, LA. (2012). Development of a gas chromatography - mass spectrometry method for the determination of carbon disulfide in the atmosphere. Microchemical Journal. 101:37-42. https://doi.org/10.1016/j.microc.2011.10.002 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://dx.doi.org/10.1016/j.microc.2011.10.002 | es_ES |
dc.description.upvformatpinicio | 37 | es_ES |
dc.description.upvformatpfin | 42 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 101 | es_ES |
dc.relation.senia | 213177 | es_ES |
dc.contributor.funder | Centro de Investigación del Medio Ambiente | |
dc.contributor.funder | Gobierno de Cantabria | |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | Fundación Bancaja | |
dc.contributor.funder | Ministerio de Ciencia e Innovación | |
dc.contributor.funder | European Commission |