Mostrar el registro sencillo del ítem
dc.contributor.author | Arias Carrascal, Karen Sulay | es_ES |
dc.contributor.author | Climent Olmedo, María José | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.contributor.author | Iborra Chornet, Sara | es_ES |
dc.date.accessioned | 2017-06-26T11:16:28Z | |
dc.date.issued | 2016-11 | |
dc.identifier.issn | 2168-0485 | |
dc.identifier.uri | http://hdl.handle.net/10251/83632 | |
dc.description.abstract | [EN] A new catalytic process to produce alkyl 5-benzyl-2-furoates has been performed through two step process that involves: a) selective oxidative esterification of 5-hydroxymethylfurfural (HMF) to 5-hydroxymethyl furoic acid methyl ester (HMFE) using Au/TiO2 as catalyst and oxygen as oxidant and b) alkylation of benzene derivatives with HMFE using zeolites as acid catalysts. The alkylation process has been carried out using large pore tridimensional zeolites such as Beta and USY, a mesoporous aluminosilicate (MCM-41), and a 2D delaminated ITQ-2 zeolite. The results showed that ITQ-2 zeolite which combines an easy product diffusion and adequate acitidy was the most active and selective catalyst to produce alkyl 5-benzyl-2-furoates. Finally, we have presented a simple protocol to prepare 5-(4-fluorobenzyl)-2-furyl methyl ketone, a key intermediate in the synthesis of S-1360, an antiviral for the treatment of AIDS, in good yield through a more sustainable method that the existing ones, starting from biomass platform molecules. | es_ES |
dc.description.sponsorship | Spanish MICINN Project CTQ:2015-67592-P, Generalitat Valenciana (Prometeo program) and Program Severo Ochoa are gratefully acknowledged. | |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS Sustainable Chemistry and Engineering | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | S-Hydroxymethylfurfural | es_ES |
dc.subject | Delaminated ITQ-2 zeolite | es_ES |
dc.subject | Aromatic alkylation | es_ES |
dc.subject | Oxidative esterification | es_ES |
dc.subject | S-1360 | es_ES |
dc.subject.classification | QUIMICA INORGANICA | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Two dimensional ITQ-2 zeolite for biomass transformation: Synthesis of alkyl 5-benzyl-2-furoates as intermediates for fine chemicals | es_ES |
dc.type | Artículo | es_ES |
dc.embargo.lift | 10000-01-01 | |
dc.embargo.terms | forever | es_ES |
dc.identifier.doi | 10.10221/acssuschemeng.6b01662 | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials | es_ES |
dc.description.bibliographicCitation | Arias Carrascal, KS.; Climent Olmedo, MJ.; Corma Canós, A.; Iborra Chornet, S. (2016). Two dimensional ITQ-2 zeolite for biomass transformation: Synthesis of alkyl 5-benzyl-2-furoates as intermediates for fine chemicals. ACS Sustainable Chemistry and Engineering. 4(11):6152-6159. https://doi.org/10.10221/acssuschemeng.6b01662 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1021/acssuschemeng.6b01662 | |
dc.description.upvformatpinicio | 6152 | es_ES |
dc.description.upvformatpfin | 6159 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 4 | es_ES |
dc.description.issue | 11 | es_ES |
dc.relation.senia | 334460 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |