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Quantitative determination of spring water quality parameters via electronic tongue

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Quantitative determination of spring water quality parameters via electronic tongue

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dc.contributor.author Carbó-Mestre, Noèlia es_ES
dc.contributor.author López-Carrero, Javier es_ES
dc.contributor.author Garcia-Castillo, F. Javier es_ES
dc.contributor.author Tormos, Isabel es_ES
dc.contributor.author Olivas, Estela es_ES
dc.contributor.author Folch, Elisa es_ES
dc.contributor.author Alcañiz Fillol, Miguel es_ES
dc.contributor.author Soto Camino, Juan es_ES
dc.contributor.author Martínez-Máñez, Ramón es_ES
dc.contributor.author Martínez-Bisbal, M.Carmen es_ES
dc.date.accessioned 2018-03-05T05:20:41Z
dc.date.available 2018-03-05T05:20:41Z
dc.date.issued 2018 es_ES
dc.identifier.uri http://hdl.handle.net/10251/98791
dc.description.abstract [EN] The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9-115 mg/L), sulfate (32-472 mg/L), fluoride (0.08-0.26 mg/L), chloride (17-190 mg/L), and sodium (11-94 mg/L) as well as pH (7.3-7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R-2 and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%. es_ES
dc.description.sponsorship The authors gratefully acknowledge the Ministerio de Economia y Competitividad and FEDER, providing funds amounting to (sic)664.525,75 for the project "Desarrollo de sistemas basados en lenguas electronicas para el control y monitorizacion del ciclo integral del agua" INNPACTO. IPT-2012-0069-310000. Moreover, the authors gratefully acknowledge the Ministerio de Economia y Competitividad and FEDER (projects MAT2015-64139-C4-1-R (MINECO/FEDER), MAT2015-64139-C4-3-R (MINECO/FEDER)), the Generalitat Valenciana (project PROMETEOII/2014/047), and CIBER-BBN (NANOPROBE project) for their financial support. en_EN
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Sensors es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Spring water es_ES
dc.subject Electronic voltammetric tongue es_ES
dc.subject Water quality control es_ES
dc.subject Partial least squares es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.subject.classification TECNOLOGIA ELECTRONICA es_ES
dc.title Quantitative determination of spring water quality parameters via electronic tongue es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/s18010040 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-3-R/ES/DESARROLLO DE EQUIPOS Y DISPOSITIVOS ELECTRONICOS COMO SISTEMA DE DETECCION Y ACTUACION BASADOS EN NUEVAS TECNOLOGIAS ELECTRONICAS. APLICACION AL AREA BIOMEDICA./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-1-R/ES/NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IPT-2012-0069-310000/ES/Desarrollo de sistemas basados en lenguas electrónicas para el control y monitorización del ciclo integral del agua. e-TONGUE4WAT/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F047/ES/Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Electrónica - Departament d'Enginyeria Electrònica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.description.bibliographicCitation Carbó-Mestre, N.; López-Carrero, J.; Garcia-Castillo, FJ.; Tormos, I.; Olivas, E.; Folch, E.; Alcañiz Fillol, M.... (2018). Quantitative determination of spring water quality parameters via electronic tongue. Sensors. 18(1):1-12. https://doi.org/10.3390/s18010040 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/s18010040 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 12 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 18 es_ES
dc.description.issue 1 es_ES
dc.identifier.eissn 1424-8220 es_ES
dc.identifier.pmid 29295592 en_EN
dc.identifier.pmcid PMC5795646 en_EN
dc.relation.pasarela S\350205 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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