Bagheri, Minoo; Melillo, Arianna; Ferrer Ribera, Rosa Belén; Masoomi, Mohammad Yaser; García Gómez, Hermenegildo(American Chemical Society, 2022-01-12)
[EN] HKUST-1 [Cu-3(BTC)(2)(H2O)(3)](n)center dot nH(2)OMeOH was submitted to thermolysis under controlled conditions at temperatures between 100 and 300 degrees C. This treatment resulted in partial ligand decarboxylation, ...
Anouar, Aicha; García-Aboal, Rocío; Atienzar Corvillo, Pedro Enrique; Franconetti, Antonio; Katir, Nadia; El Kadib, Abdelkrim; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(Wiley-VCH Verlag GmbH & Co. KGaA, 2022-05)
[EN] In the context of diminishing atmospheric CO2 emissions, there is an urgent need to develop processes that can be carried out at a scale commensurate with appropriate CO2 volumes. One possible reaction is the ...
[EN] 5-hydroxymethylfurfural (HMF) has been successfully valorized into 3-hydroxymethylcyclopentylamine through a one-pot cascade process in aqueous phase by coupling the hydrogenative ring-rearrangement of HMF into ...
[EN] The administration of cytotoxic drugs in classical chemotherapy is frequently limited by water solubility, low plasmatic stability, and a myriad of secondary effects associated with their diffusion to healthy tissue. ...
Cerrillo, J. L.; Palomares Gimeno, Antonio Eduardo; Rey Garcia, Fernando(Elsevier, 2020-10-01)
[EN] In this work, different Ag-zeolites have been evaluated as biocide materials against two common bacteria, displaying an excellent bactericidal activity in different media. The results demonstrate that the amount of ...
[EN] The behavior of single Pt atoms and small Pt clusters was investigated for high-temperature oxidations. The high stability of these molecular sites in CHA is a key to intrinsic structure-performance descriptions of ...
Toldrá-Reig, Fidel; Serra Alfaro, José Manuel(American Chemical Society, 2018-12)
[EN] This work presents a multidevice potentiometric sensor consisting of Fe0.7Cr1.3O3/8YSZ//8YSZ//Pt to detect selectively C2H4 with a low cross-sensitivity to CO in diesel exhaust gases. The device has been designed as ...
Du, Xiangze; Peng, Lu; Hu, Jiajun; Peng, Yong; Primo Arnau, Ana Maria; Li, Dan; Albero-Sancho, Josep; Hu, Changwei; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2022-08-18)
[EN] Electrochemical CO2 reduction is an appealing approach to diminish CO2 emissions, while obtaining valuable chemicals and fuels from renewable electricity. However, efficient electrocatalysts exhibiting high selectivity ...
[EN] A multidimensional extra-large pore germanosilicate, denoted ITQ-56, has been synthesized by using modified memantine as an organic structure-directing agent. ITQ-56 crystallizes as plate-like nanocrystals. Its structure ...
Rojas-Buzo, Sergio; Bohigues, Benjamin; Lopes, Christian W.; Meira, Débora M.; Boronat Zaragoza, Mercedes; Moliner Marin, Manuel; Corma Canós, Avelino(The Royal Society of Chemistry, 2021-08-07)
[EN] The Lewis/Bronsted catalytic properties of the Metal-Organic Framework (MOF) nodes can be tuned by simply controlling the solvent employed in the synthetic procedure. In this work, we demonstrate that Hf-MOF-808 can ...
[EN] The selective oxidation of propene to propene oxide (PO) is an industrially relevant and still challenging reaction that requires the design of highly specific catalysts able to improve simultaneously activity and ...
[EN] The light olefin product distribution of the methanol-to-olefin (MTO) reaction catalyzed by acid zeolites and zeotypes depends on the nature of the entrapped hydrocarbon pool species that act as co-catalysts. The ...
[EN] Lanthanum tungstate (La6WO12) is a promising material for the development of hydrogen separation membranes, proton ceramic electrolyzer cells and protonic ceramic fuel cells due to its interesting transport properties ...
Peng, Lu; Garcia-Baldovi, Hermenegildo; Dhakshinamoorthy, Amarajothi; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(American Chemical Society, 2022-04-05)
[EN] Two tridimensional N-doped porous carbon sponges (3DC-X) have been prepared by using cetyltrimethylammonium chloride ( CTAC) and cetyltrimethylammonium bromide (CTAB) as soft templates and alginate to replicate the ...
[EN] Non-noble bimetallic CoW nanoparticles (NPs) partially embedded in a carbon matrix (cow@c) have been prepared by a facile hydrothermal carbon-coating methodology followed by pyrolysis under an inert atmosphere. The ...
Simancas, Raquel; Nishitoba, Toshiki; Park, Sungsik; Kondo, Junko N.; Rey Garcia, Fernando; Gies, Hermann; Yokoi, Toshiyuki(Elsevier, 2021-04)
[EN] To fabricate a novel metallosilicate zeolite with a tridirectional pore system of 8- and 10-ring channels, direct incorporation of B, Al and Ga into small and medium pore ITQ-52 zeolite with the IFW-type topology was ...
Moura, P.A.S.; Rodríguez-Aguado, E.; Maia, D.A.S.; Melo, D. C.; Singh, R.; Valencia Valencia, Susana; Webley, P.A.; Rey Garcia, Fernando; Bastos-Neto, M.; Rodriguez-Castellón, E.; Azevedo, D.C.S.(Elsevier, 2022-05-01)
[EN] Zeolites are well known crystalline aluminosilicates, which may be used in processes that take advantage of their molecular sieving effect, such as natural gas drying. They are often used in cyclic processes that swing ...
W. Lopes, Christian; Martinez-Ortigosa, Joaquin; Góra-Marek, Kinga; Tarach, Karolina; Vidal Moya, José Alejandro; Palomares Gimeno, Antonio Eduardo; Agostini, Giovanni; Blasco Lanzuela, Teresa; Rey Garcia, Fernando(The Royal Society of Chemistry, 2021-12-14)
[EN] Supported silver species are among the most promising catalysts for the depletion of ammonia emission by selective catalytic oxidation (NH3-SCO). Here, an investigation on the influence of small pore CHA and RHO zeolite ...