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Mostrando ítems 1-8 de 8

Click amidations, esterifications and one¿pot reactions catalyzed by Cu salts and multimetal-organic frameworks (M-MOFs)

Greco, Rossella; Tiburcio, Estefanía; Palomar-De Lucas, Brenda; Ferrando-Soria, Jesús; Armentano, Donatella; Pardo, Emilio; Leyva Perez, Antonio (Elsevier, 2022-04)

[EN] Amides and esters are prevalent chemicals in Nature, industry and academic laboratories. Thus, it is not surprising that a plethora of synthetic methods for these compounds has been developed along the years. However, ...
Crystallographic Visualization of a Double Water Molecule Addition on a Pt-1-MOF during the Low-temperature Water-Gas Shift Reaction

Bilanin-Artigado, Cristina; Tiburcio, Estefanía; Ferrando-Soria, Jesús; Armentano, Donatella; Leyva Perez, Antonio; Pardo, Emilio (John Wiley & Sons, 2021-02-18)

[EN] The low-temperature water-gas shift reaction (WGSR, CO+H2O H-2+CO2) is considered a very promising reaction -candidate for fuel cells- despite an efficient and robust catalyst is still desirable. One of the more ...
Epoxidation vs. dehydrogenation of allylic alcohols: heterogenization of the VO(acac)(2) catalyst in a metal-organic framework

Negro, Cristina; Bilanin-Artigado, Cristina; Qu, Xiaoni; Oliver-Meseguer, Judit; Ferrando-Soria, Jesus; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio (The Royal Society of Chemistry, 2022-05-05)

[EN] Allylic alcohol epoxidation and dehydrogenation reactivity is distinguished when VO(acac)(2) is used in solution or anchored in a metal-organic framework (MOF). The chemical mechanism depends on the electronic profile ...
Hydrolase-like catalysis and structural resolution of natural products by a metal-organic framework

Mon-Conejero, Marta; Bruno, Rosaria; Sanz-Navarro, Sergio; Negro, Cristina; Ferrando-Soria, Jesus; Bartella, Lucia; Di Donna, Leonardo; Prejano, Mario; Marino, Tiziana; Leyva Perez, Antonio; Armentano, Donatella; Pardo, Emilio (Nature Publishing Group, 2020-06-17)

[EN] The exact chemical structure of non-crystallising natural products is still one of the main challenges in Natural Sciences. Despite tremendous advances in total synthesis, the absolute structural determination of a ...
Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

Viciano-Chumillas, Marta; Liu, Xiangyu; Leyva Perez, Antonio; Armentano, Donatella; Ferrando-Soria, Jesús; Pardo, Emilio (Elsevier, 2022-01-15)

[EN] The synthesis of mixed-component metal-organic frameworks (MOFs) -including multivariate MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and metals MOFs- is becoming a very active research ...
MOF-Stabilized Perfluorinated Palladium Cages Catalyze the Additive-Free Aerobic Oxidation of Aliphatic Alcohols to Acids

Greco, Rossella; Tiburcio-Fortes, Estefania; Fernandez, Antonio; Marini, Carlo; Vidal Moya, José Alejandro; Oliver-Meseguer, Judit; Armentano, Donatella; Pardo, Emilio; Ferrando-Soria, Jesus; Leyva Perez, Antonio (John Wiley & Sons, 2022-01)

[EN] Extremely high electrophilic metal complexes, composed by a metal cation and very electron poor sigma-donor ancillary ligands, are expected to be privileged catalysts for oxidation reactions in organic chemistry. ...
Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Tiburcio, Estefanía; Greco, Rossella; Mon-Conejero, Marta; Ballesteros-Soberanas, Jordi; Ferrando-Soria, Jesus; Lopez-Haro, Miguel; Hernández-Garrido, Juan Carlos; Oliver-Meseguer, Judit; Marini, Carlo; Boronat Zaragoza, Mercedes; Armentano, Donatella; Leyva Perez, Antonio; Pardo, Emilio (American Chemical Society, 2021-02-04)

[EN] Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and ...
The effect of NGATHA altered activity on auxin signaling pathways within the Arabidopsis gynoecium

Martínez Fernández, Irene; Sanchis, Sofía; Marini, Naciele; Balanzá Pérez, Vicente; Ballester Fuentes, Patricia; Navarrete Gomez, Maria Luisa; Oliveira, Antonio C.; Colombo, Lucia; Ferrandiz Maestre, Cristina (Frontiers Media, 2014-05-21)

[EN] The four NGATHA genes (NGA) form a small subfamily within the large family of B3-domain transcription factors of Arabidopsis thaliana. NGA genes act redundantly to direct the development of the apical tissues of the ...