Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; Asiri, Abdullah M.; García Gómez, Hermenegildo(MDPI AG, 2021-06)
[EN] Cu-3(BTC)(2) (BTC: 1,3,5-benzenetricarboxylate) as a heterogeneous catalyst in the presence of cesium carbonate as a base is reported for the borylation of alpha,beta-conjugated enones by bis(pinacolato)diboron ...
[EN] We report the formation of an ultrahigh CO2-loaded pure-SiO2, silicalite-1 structure at high pressure (0.7 GPa) from the interaction of empty zeolite and fluid CO, medium. The CO2-filled structure was characterized ...
Garcia-Mulero, Ana; Rendón-Patiño, Alejandra; Asiri, Abdullah M.; Primo Arnau, Ana Maria; García Gómez, Hermenegildo(American Chemical Society, 2021-10-20)
[EN] Carbon-based solar photocatalysts for overall water splitting could provide H2 as an energy vector in a clean and sustainable way. Band engineering to align energy levels can be achieved, among other ways, by doping. ...
[EN] A series of highly crystalline, porous, hafnium-based metal-organic frameworks (Hf-MOFs) have been shown to catalyze the transfer hydrogenation reaction of levulinic ester to produce -valerolactone by using isopropanol ...
Peng, Lu; Jurca, Bogdan; Primo Arnau, Ana Maria; Gordillo, Alvaro; Parvulescu, Vasile I.; García Gómez, Hermenegildo(American Chemical Society, 2021-07-19)
[EN] Graphitic carbons are suitable supports of metal nanoparticles with catalytic activity. In the present study, the preparation of N-doped graphitic carbon supporting clusters of Fe-Co alloys starting from biomass waste ...
Jurca, Bogdan; Peng, Lu; Primo Arnau, Ana Maria; Gordillo, Alvaro; Parvulescu, Vasile I.; García Gómez, Hermenegildo(American Chemical Society, 2021-08-11)
[EN] Pyrolysis of chitosan containing various loadings of Co and Fe renders Co-Fe alloy nanoparticles supported on N-doped graphitic carbon. Transmission electron microscopy (TEM) images show that the surface of Co-Fe NPs ...
[EN] The chemistry between layered MWW zeolite and carbon black pearls (BP 2000) as an inexpensive hard template was investigated to develop a rational one-pot synthesis of MCM-22 microspheres. The characterization results ...
Bagheri, Minoo; Masoomi, Mohammad Yaser; Domínguez Torres, Esther; García Gómez, Hermenegildo(Royal Society of Chemistry, 2021-09-21)
[EN] The catalytic activity of metal-organic frameworks (MOFs) depends largely on the presence of structural defects. In the present study, cobalt based metal-organic framework TMU-10, [Co-6(oba)(5)(OH)(2)(H2O)(2)(DMF)(4 ...
García, Teresa; García-Aboal, Rocío; Albero-Sancho, Josep; Atienzar Corvillo, Pedro Enrique; García Gómez, Hermenegildo(MDPI AG, 2020-05)
[EN] Films or powders of hybrid methylammonium copper halide perovskite exhibit photocatalytic activity for overall water splitting in the vapor phase in the absence of any sacrificial agent, resulting in the generation ...