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Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides

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Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides

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Alvaro Rodríguez, MM.; Aprile ., C.; Corma Canós, A.; Ferrer Ribera, RB.; García Gómez, H. (2006). Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides. Journal of Catalysis. 245(1):249-252. doi:10.1016/j.jcat.2006.10.003

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Title: Influence of radical initiators in gold catalysis: Evidence supporting trapping of radicals derived from azobis(isobutyronitrile) by gold halides
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Gold halides (AuCl3, HAuCl4, and AuCl) efficiently trap the radicals generated in the room-temperature photolysis of azobis(isobutyronitrile) (AIBN) to give an organogold H[(CH3)(2)CCN](2)AuCl2 compound that has been ...[+]
Subjects: Gold catalysis , Radical trapping , Radical initiators , Organogold
Copyrigths: Reserva de todos los derechos
Source:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2006.10.003
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/j.jcat.2006.10.003
Type: Artículo

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