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A study of some fundamental physicochemical variables on the morphology of mesoporous silica nanoparticles MCM-41 type

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A study of some fundamental physicochemical variables on the morphology of mesoporous silica nanoparticles MCM-41 type

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dc.contributor.author Beltrán-Osuna, A.A. es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.contributor.author Perilla-Perilla, Jairo Ernesto es_ES
dc.date.accessioned 2018-05-13T04:28:06Z
dc.date.available 2018-05-13T04:28:06Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1388-0764 es_ES
dc.identifier.uri http://hdl.handle.net/10251/101858
dc.description.abstract [EN] All variables affecting the morphology of mesoporous silica nanoparticles (MSN) should be carefully analyzed in order to truly tailored design their mesoporous structure according to their final use. Although complete control on MCM-41 synthesis has been already claimed, reproducibility and repeatability of results remain a big issue due to the lack of information reported in literature. Stirring rate, reaction volume, and system configuration (i.e., opened or closed reactor) are three variables that are usually omitted, making the comparison of product characteristics difficult. Specifically, the rate of solvent evaporation is seldom disclosed, and its influence has not been previously analyzed. These variables were systematically studied in this work, and they were proven to have a fundamental impact on final particle morphology. Hence, a high degree of circularity (C = 0.97) and monodispersed particle size distributions were only achieved when a stirring speed of 500 rpm and a reaction scale of 500 mL were used in a partially opened system, for a 2 h reaction at 80 degrees C. Well-shaped spherical mesoporous silica nanoparticles with a diameter of 95 nm, a pore size of 2.8 nm, and a total surface area of 954 m(2) g(-1) were obtained. Final characteristics made this product suitable to be used in biomedicine and nanopharmaceutics, especially for the design of drug delivery systems. es_ES
dc.description.sponsorship This study was funded partially by Departamento Administrativo de Ciencia Tecnología e Innovación–COLCIENCIAS (recipient, Angela A. Beltrán-Osuna); Ministerio de Economía y Competitividad, MINECO, research number MAT2016-76039-C4-1-R (Recipient, José L. Gómez-Ribelles); and Universidad Nacional de Colombia, grant number DIB201010021438 (Recipient, Jairo E. Perilla). es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Journal of Nanoparticle Research es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject MSN es_ES
dc.subject Partially opened system es_ES
dc.subject Reaction volume es_ES
dc.subject Stirring rate es_ES
dc.subject MCM-41 es_ES
dc.subject Mesoporous silica nanoarticles es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title A study of some fundamental physicochemical variables on the morphology of mesoporous silica nanoparticles MCM-41 type es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s11051-017-4077-2 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76039-C4-1-R/ES/BIOMATERIALES PIEZOELECTRICOS PARA LA DIFERENCIACION CELULAR EN INTERFASES CELULA-MATERIAL ELECTRICAMENTE ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNAL//DIB 201010021438/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2018-11-25 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Beltrán-Osuna, A.; Gómez Ribelles, JL.; Perilla-Perilla, JE. (2017). A study of some fundamental physicochemical variables on the morphology of mesoporous silica nanoparticles MCM-41 type. Journal of Nanoparticle Research. 19(12):1-14. https://doi.org/10.1007/s11051-017-4077-2 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s11051-017-4077-2 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 14 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 12 es_ES
dc.relation.pasarela S\357753 es_ES
dc.contributor.funder Departamento Administrativo de Ciencia, Tecnología e Innovación, Colombia es_ES
dc.contributor.funder Universidad Nacional de Colombia es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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