Synthesis of Perfectly Oriented MAPb0.93Cr0.07Br3 Perovskite Crystals for Thin-Film Photovoltaic Applications

Abstract

[EN] Wide band gap methylammonium lead halide perovskites (CH3NH3PbX3, X=halogen; CH3NH3: MA) are interesting materials for photovoltaic applications. They have recently gained substantial attention because of their high efficiency, low cost, superior optical properties. The most attractive and representative perovskites are methylammonium lead halides (CH3NH3PbX3,) denoted as MAPbX3, X = Br, Cl, I. usually the optical and structural properties of CH3NH3PbBr3 can be adjusted by introducing other extrinsic ions such as chloride and bromide. In this work, instead of replacing the halogens I or Cl with bromine (Br) as usual, we preferred to act on the post-transition metal (Pb). To this end, we replaced lead with chromium (Cr) which is a transition metal and may have the same oxidation state (+2) as lead. MAPb0.93Cr0.07Br3 thin films were deposited on ITO substrate by the spin coating process. X-ray diffraction analyses indicated the formation of a cubic perovskite with space group Pm3 m. The structural analysis reveals films with (110) and (220) as main peaks. Deposited films showed a strong absorbance in the UV¿vis range. The band gap values were estimated from absorbance measurements. It was found between 1.60 and 1.80 eV. SEM analysis shows a morphology with good coverage and no apparent crystal orientation.