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Experimental Quantification of the Effect of Nonlinearities on the EIS Spectra of the Cathodic Electrode of an Alkaline Electrolyzer

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Experimental Quantification of the Effect of Nonlinearities on the EIS Spectra of the Cathodic Electrode of an Alkaline Electrolyzer

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dc.contributor.author Giner-Sanz, J.J. es_ES
dc.contributor.author Ortega, E.M. es_ES
dc.contributor.author Pérez-Herranz, V. es_ES
dc.date.accessioned 2018-05-28T04:17:50Z
dc.date.available 2018-05-28T04:17:50Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1615-6846 es_ES
dc.identifier.uri http://hdl.handle.net/10251/102743
dc.description.abstract [EN] Electrochemical impedance spectroscopy (EIS) is a very powerful tool to study the behavior of electrochemical systems. According to Ohm¿s generalized law, the impedance concept is only valid if the linearity condition is met. In the case that the linearity condition is not achieved, the obtained impedance spectra will present distortions which may lead to biased or even erroneous results and conclusions. In this work, an experimental quantification of the effect of nonlinearities on EIS spectra was performed in order to determine the order of magnitude of the effect of the nonlinearity of the system on the obtained spectra of the cathodic electrode of an alkaline electrolyzer. es_ES
dc.description.sponsorship The authors are very grateful to the Generalitat Valenciana for its economic support in form of Vali+d grant (Ref: ACIF-2013-268). en_EN
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Fuel Cells es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alkaline Electrolyzer es_ES
dc.subject Electrochemical Impedance Spectroscopy es_ES
dc.subject Experimental Quantification es_ES
dc.subject Nonlinearity es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Experimental Quantification of the Effect of Nonlinearities on the EIS Spectra of the Cathodic Electrode of an Alkaline Electrolyzer es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/fuce.201600137 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2010%2F023/ES/GENERACION DE HIDROGENO: DESARROLLO DE NUEVOS MATERIALES DE ELECTRODO PARA LA REACCION DE EVOLUCION DE HIGROGENO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2013%2F268/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Giner-Sanz, J.; Ortega, E.; Pérez-Herranz, V. (2017). Experimental Quantification of the Effect of Nonlinearities on the EIS Spectra of the Cathodic Electrode of an Alkaline Electrolyzer. Fuel Cells. 17(3):391-401. https://doi.org/10.1002/fuce.201600137 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/fuce.201600137 es_ES
dc.description.upvformatpinicio 391 es_ES
dc.description.upvformatpfin 401 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 17 es_ES
dc.description.issue 3 es_ES
dc.relation.pasarela S\341229 es_ES
dc.contributor.funder Generalitat Valenciana es_ES


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