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Production of High Quality Syncrude from Lignocellulosic Biomass

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Production of High Quality Syncrude from Lignocellulosic Biomass

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dc.contributor.author Mathieu, Yannick es_ES
dc.contributor.author Sauvanaud, Laurent L.A. es_ES
dc.contributor.author Humphreys, Len es_ES
dc.contributor.author Rowlands, William es_ES
dc.contributor.author Maschmeyer, T. es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2018-06-01T04:28:10Z
dc.date.available 2018-06-01T04:28:10Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1867-3880 es_ES
dc.identifier.uri http://hdl.handle.net/10251/103151
dc.description.abstract [EN] Wood chips were hydrothermally treated in near critical point water in the presence of a catalyst to yield a raw biocrude, containing a wide range of organic components. This product was subsequently distilled to remove its heaviest fraction, which tends to yield chary products if heated above 350 degrees C. The biocrude obtained has an oxygen content of 12wt% and was subsequently hydrotreated to obtain a hydrocarbon stream. Varying the hydrotreatment operating conditions and catalyst yielded a deoxygenated syncrude which quality improved with operation severity. The hydroprocessed stream produced under very mild conditions can be further upgraded in conventional refinery operations while the stream produced after more severe hydrotreatment can be mixed with conventional diesel. This proof of concept was demonstrated with commercial hydrotreating catalysts, operating between 350 and 380 degrees C, 40 to 120bar pressure and 0.5 to 1h(-1) contact time. es_ES
dc.description.sponsorship The authors thank Licella for material and financial support, as well as providing the biocrude used for the hydrotreating experiments. Licella gratefully acknowledges support from the Australian Government in the form of funding as part of the Advanced Biofuels Investment Readiness Program, received through the Australian Renewable Energy Agency (ARENA). Financial support by the Spanish Government-MINECO through program "Severo Ochoa" (SEV 2012-0267), CTQ2015-70126-R (MINECO/FEDER), and by the Generalitat Valenciana through the Prometeo program (PROMETEOII/2013/011) is also acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biofuel es_ES
dc.subject Biomass valorization es_ES
dc.subject Hydrotreatment es_ES
dc.subject Llignocellulose es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Production of High Quality Syncrude from Lignocellulosic Biomass es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cctc.201601677 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F011/ES/Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Mathieu, Y.; Sauvanaud, LL.; Humphreys, L.; Rowlands, W.; Maschmeyer, T.; Corma Canós, A. (2017). Production of High Quality Syncrude from Lignocellulosic Biomass. ChemCatChem. 9(9):1574-1578. https://doi.org/10.1002/cctc.201601677 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/cctc.201601677 es_ES
dc.description.upvformatpinicio 1574 es_ES
dc.description.upvformatpfin 1578 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 9 es_ES
dc.relation.pasarela S\358643 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Australian Renewable Energy Agency es_ES
dc.contributor.funder European Regional Development Fund
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