Lo-Presti, M.; Martínez-Máñez, R.; Ros-Lis, JV.; Batista, RMF.; Costa, SPG.; Raposo, MMM.; Sancenón Galarza, F. (2018). A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution. New Journal of Chemistry. 42(10):7863-7868. https://doi.org/10.1039/c7nj04699e
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/103743
Title:
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A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
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Author:
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Lo-Presti, Maria
Martínez-Máñez, Ramón
Ros-Lis, José Vicente
Batista, Rosa M. F.
Costa, Susana P. G.
Raposo, M. Manuela M.
Sancenón Galarza, Félix
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UPV Unit:
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Universitat Politècnica de València. Departamento de Química - Departament de Química
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Issued date:
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Abstract:
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[EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a
boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle.
Acetonitrile and ...[+]
[EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a
boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle.
Acetonitrile and water¿acetonitrile 95 : 5 v/v solutions of the probe showed an ICT band in the visible
zone and are nearly non-emissive. When acetonitrile was used as a solvent, addition of Hg(II) and
trivalent metal cations induced an hypsochromic shift of the absorption band and moderate emission
enhancements. A highly selective response was obtained when using competitive media such as water¿
acetonitrile 95 : 5 v/v. In this case only Hg(II) induced a hypsochromic shift of the absorption band and a
marked emission enhancement.
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Subjects:
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Mercury
,
Bodipy
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Water
,
Coordination
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Copyrigths:
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Reserva de todos los derechos
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Source:
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New Journal of Chemistry. (issn:
1144-0546
)
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DOI:
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10.1039/c7nj04699e
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Publisher:
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The Royal Society of Chemistry
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Publisher version:
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http://doi.org/10.1039/c7nj04699e
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Project ID:
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info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-1-R/ES/NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO/
info:eu-repo/grantAgreement/FCT/COMPETE/132953/PT/2013-2014/
info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F047/ES/Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos/
info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F79333%2F2011/PT/SYNTHESIS AND CHARACTERIZATION OF NOVEL HETEROCYCLE-BASED TWO-PHOTON ABSORBING (TPA) ORGANIC MOLECULES FOR NANOSCALE IMAGING AND OPTICAL DATA STORAGE APPLICATIONS/
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Thanks:
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We thank the Spanish Government (MAT2015-64139-C4-1-R) and Generalitat Valenciana (PROMETEOII/2014/047). M. L. P. thanks Generalitat Valenciana for her Grisolia fellowship. Thanks are also due to Fundaça˜o para a Cieˆncia ...[+]
We thank the Spanish Government (MAT2015-64139-C4-1-R) and Generalitat Valenciana (PROMETEOII/2014/047). M. L. P. thanks Generalitat Valenciana for her Grisolia fellowship. Thanks are also due to Fundaça˜o para a Cieˆncia e Tecnologia (Portugal) for financial support to the Portuguese NMR network (PTNMR, Bruker Avance III 400-Univ. Minho), FCT and FEDER (European Fund for Regional Development)-COMPETEQRENEU for financial support to the research centre CQ/UM [PEst-C/ QUI/UI0686/2013 (FCOMP-01-0124-FEDER-037302)], and a postdoctoral grant to R. M. F. Batista (SFRH/BPD/79333/2011).
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Type:
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Artículo
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