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Disintegration in compost conditions and water uptake of green composites from poly(lactic acid) and hazelnut shell flour

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Disintegration in compost conditions and water uptake of green composites from poly(lactic acid) and hazelnut shell flour

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dc.contributor.author Balart, J.F. es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.contributor.author Fombuena, Vicent es_ES
dc.contributor.author Boronat, Teodomiro es_ES
dc.contributor.author Sanchez-Nacher, Lourdes es_ES
dc.date.accessioned 2018-06-17T04:21:37Z
dc.date.available 2018-06-17T04:21:37Z
dc.date.issued 2018 es_ES
dc.identifier.issn 1566-2543 es_ES
dc.identifier.uri http://hdl.handle.net/10251/104223
dc.description.abstract [EN] Green composites of poly(lactic acid)-PLA and hazelnut shell flour (HSF) with and without epoxidized linseed oil (ELO) as plasticizer/compatibilizer were subjected to different aging conditions such as water uptake by immersion and disintegration in compost soil. The effect of the hydrolytic degradation was analyzed by measuring the weight gain as a function of the immersion time in water and calculating the corresponding diffusion coefficients. As expected, the water diffusion coefficient increases with HSF content while no remarkable change is obtained for plasticized compositions with ELO. Differential scanning calorimetry reveals a noticeable increase in crystallinity after the degradation process by water immersion. Degradation in controlled compost soil was followed thorough measurements of weight changes. In general, the weight change for a particular degradation time is lower as the HSF content increases. In addition, presence of ELO as plasticizer/compatibilizer delays the degradation process in compost soil. Scanning electron microscopy highlighted a noticeable deterioration of aged samples after 2 weeks with multiple crack formation and high surface abrasion due to microbial activity after 4 weeks. es_ES
dc.description.sponsorship This research was supported by the Ministry of Economy and Competitiveness - MINECO, Ref: MAT2014-59242-C2-1-R. Authors also thank to "Conselleria d'Educacio, Cultura i Esport" - Generalitat Valenciana, Ref: GV/2014/008 for financial support.
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Journal of Polymers and the Environment es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Degradation process es_ES
dc.subject Epoxidized linseed oil es_ES
dc.subject Hazelnut shells es_ES
dc.subject Hydrolytic degradation es_ES
dc.subject Microbial activities es_ES
dc.subject Poly lactic acid es_ES
dc.subject Water diffusion coefficients es_ES
dc.subject Water uptake es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Disintegration in compost conditions and water uptake of green composites from poly(lactic acid) and hazelnut shell flour es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10924-017-0988-3 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-59242-C2-1-R/ES/TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2014%2F008/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2019-02-01 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Balart, J.; Montanes, N.; Fombuena, V.; Boronat, T.; Sanchez-Nacher, L. (2018). Disintegration in compost conditions and water uptake of green composites from poly(lactic acid) and hazelnut shell flour. Journal of Polymers and the Environment. 26(2):701-715. https://doi.org/10.1007/s10924-017-0988-3 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1007/s10924-017-0988-3 es_ES
dc.description.upvformatpinicio 701 es_ES
dc.description.upvformatpfin 715 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 26 es_ES
dc.description.issue 2 es_ES
dc.relation.pasarela S\336342 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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