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Layered hybrid materials with nanotechnological applications: use of disilane precursors as pillaring agents

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Layered hybrid materials with nanotechnological applications: use of disilane precursors as pillaring agents

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dc.contributor.author Urbano Diaz es_ES
dc.contributor.author Angel Cantin es_ES
dc.contributor.author Teresa Garcia es_ES
dc.contributor.author Avelino Corma es_ES
dc.date.accessioned 2018-07-06T04:25:30Z
dc.date.available 2018-07-06T04:25:30Z
dc.date.issued 2008 es_ES
dc.identifier.issn 0167-2991 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105344
dc.description.abstract [EN] A new family of layered organic-inorganic hybrid materials was synthesized using bridged silsesquioxane compounds (disilanes) as pillars which are intercalated between magadiite layers. The organic-inorganic precursors react with the surface silanol groups of the inorganic layers of silicate, bonding covalently with them. The preparation process was followed by DRX and the presence of organic linkers was confirmed by chemical and thermogravimetrical analyses, (13)C and (29)Si NMR spectroscopy. Micro and mesoporosity were also generated due to the existence of interlayer galleries. The layered hybrid materials exhibited thermally stable networks. The resultant materials can be of interest as acid or basic catalysts, sensors and for non linear optics. es_ES
dc.description.sponsorship Financial support by the Spanish Government (MAT2006-26599) and the Generalitat Valenciana (GV/2007/004) are gratefully acknowledged. TG is grateful by the JAE predoctoral fellowship from CSIC
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Studies in Surface Science and Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Hybrid es_ES
dc.subject Organic-inorganic es_ES
dc.subject Layered materials es_ES
dc.subject Bridged silsesquioxanes es_ES
dc.subject Pillaring es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Layered hybrid materials with nanotechnological applications: use of disilane precursors as pillaring agents es_ES
dc.type Artículo es_ES
dc.type Comunicación en congreso es_ES
dc.identifier.doi 10.1016/S0167-2991(08)80211-X es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//MAT2006-26599-E/ES/NUEVOS ZEOTIPOS HIBRIDOS ORGANICOS-INORGANICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//GV%2F2007%2F004/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GV//2007/004/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Urbano Diaz; Angel Cantin; Teresa Garcia; Avelino Corma (2008). Layered hybrid materials with nanotechnological applications: use of disilane precursors as pillaring agents. Studies in Surface Science and Catalysis. 174A:337-340. https://doi.org/10.1016/S0167-2991(08)80211-X es_ES
dc.description.accrualMethod S es_ES
dc.relation.conferencename 4th International FEZA Conference es_ES
dc.relation.conferencedate September 02-06,2008 es_ES
dc.relation.conferenceplace Paris, Francia es_ES
dc.relation.publisherversion https://doi.org/10.1016/S0167-2991(08)80211-X es_ES
dc.description.upvformatpinicio 337 es_ES
dc.description.upvformatpfin 340 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 174A es_ES
dc.relation.pasarela S\34419 es_ES
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
dc.contributor.funder Generalitat Valenciana es_ES


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