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Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C C coupling of vinylsilanes and halobenzenes leading to styrenes

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Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C C coupling of vinylsilanes and halobenzenes leading to styrenes

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Grirrane, A.; García Gómez, H.; Corma Canós, A. (2013). Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C C coupling of vinylsilanes and halobenzenes leading to styrenes. Journal of Catalysis. 302:49-57. doi:10.1016/j.jcat.2013.02.019

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Title: Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C C coupling of vinylsilanes and halobenzenes leading to styrenes
Author: Grirrane, Abdessamad García Gómez, Hermenegildo Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Palladium nanoparticles supported on magnesia is a highly efficient solid, reusable catalyst to promote in the absence of phosphine ligands the coupling of vinylsilanes with iodo- and bromobenzenes to form styrenes.
Subjects: Hiyama coupling , Vinylsilane coupling , Palladium catalyst , Styrene formation
Copyrigths: Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
Source:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2013.02.019
Publisher:
Elsevier
Publisher version: http://dx.doi.org/10.1016/j.jcat.2013.02.019
Project ID:
Ministerio de Ciencia e Innovación/CTQ2012-32316
Thanks:
Financial support by Spanish Ministry of Science and Innovation (Consolider MULTICAT and CTQ 2012-32316) is gratefully acknowledged. The Generalidad Valenciana is also thanked for partial financial support (Prometeo Grant).[+]
Type: Artículo

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