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Mechanistic differences between methanol and dimethyl ether carbonylation in side pockets and large channels of mordenite.

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Mechanistic differences between methanol and dimethyl ether carbonylation in side pockets and large channels of mordenite.

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Boronat Zaragoza, M.; Martínez, C.; Corma Canós, A. (2011). Mechanistic differences between methanol and dimethyl ether carbonylation in side pockets and large channels of mordenite. Physical Chemistry Chemical Physics. 13(7):2603-2612. doi:10.1039/C0CP01996H

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/105397

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Title: Mechanistic differences between methanol and dimethyl ether carbonylation in side pockets and large channels of mordenite.
Author: Boronat Zaragoza, Mercedes Martínez, Cristina Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The activity and selectivity towards carbonylation presented by Bronsted acid sites located inside the 8MR pockets or in the main 12MR channels of mordenite is studied by means of quantum-chemical calculations, and ...[+]
Copyrigths: Cerrado
Source:
Physical Chemistry Chemical Physics. (issn: 1463-9076 )
DOI: 10.1039/C0CP01996H
Publisher:
The Royal Society of Chemistry
Publisher version: http://doi.org/10.1039/C0CP01996H
Thanks:
The authors thank CICYT (MAT 2006-14274-C02-01) and Consolider-Ingenio-2010 (project MULTICAT) for financial support.
Type: Artículo

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