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Monoalkylations with alcohols by a cascade reaction on bifunctional solid catalysts: Reaction kinetics and mechanism

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Monoalkylations with alcohols by a cascade reaction on bifunctional solid catalysts: Reaction kinetics and mechanism

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Corma Canós, A.; Ródenas Torralba, T.; Sabater Picot, MJ. (2011). Monoalkylations with alcohols by a cascade reaction on bifunctional solid catalysts: Reaction kinetics and mechanism. Journal of Catalysis. 279(2):319-327. doi:10.1016/j.jcat.2011.01.029

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Title: Monoalkylations with alcohols by a cascade reaction on bifunctional solid catalysts: Reaction kinetics and mechanism
Author: Corma Canós, Avelino Ródenas Torralba, Tania Sabater Picot, Mª José
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] A bifunctional catalytic system formed by Pd on MgO catalyzes the cascade process between benzyl alcohol and phenylacetonitrile, diethylmalonate and nitromethane, to give the respective alpha-monoalkylated products ...[+]
Subjects: Bifunctional catalyst , Pd-MgO , Cascade reaction , Hydrogen transfer , Metal nanoparticle , Palladium dihydride , Basic supports
Copyrigths: Cerrado
Source:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2011.01.029
Publisher:
ACADEMIC PRESS INC ELSEVIER SCIENCE
Publisher version: http://doi.org/10.1016/j.jcat.2011.01.029
Thanks:
Financial support by Ministerio de Educacion y Ciencia e Innovacion (Project MIYCIN, CSD2009-00050; PROGRAMA CONSOLIDER.INGENIO 2009) and Generalidad Valenciana (GV PROMETEO/2008/130) is gratefully acknowledged. T.R. thanks ...[+]
Type: Artículo

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