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Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C-C Bond Forming Reactions and Tandem Processes

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Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C-C Bond Forming Reactions and Tandem Processes

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dc.contributor.author Gaona Cordero, Aide es_ES
dc.contributor.author Díaz Morales, Urbano Manuel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2018-07-09T06:42:45Z
dc.date.available 2018-07-09T06:42:45Z
dc.date.issued 2017 es_ES
dc.identifier.issn 0897-4756 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105536
dc.description.abstract [EN] Novel bifunctional acid base monolayered hybrid catalysts (MLHMs), based on associated individual (organo)aluminosilicate sheets with amino and sulfonic pending groups located in the interlayer space, have been successfully prepared by direct alkaline hydrothermal synthesis and evaluated in consecutive catalytic transformations. Different characterization techniques such as chemical and thermogravimetrical analyses, X-ray diffraction, TEM microscopy, nuclear magnetic resonance (NMR), temperature programmed desorption of CO2 and NH3 (TPD), and textural measurements were used to show the physicochemical and structural nature of the materials, evidencing their effectiveness as functional acid, base, and acid base catalysts for different one pot two-step tandem reactions, which were performed in the presence of only one active and recoverable lamellar-type hybrid solid catalyst. es_ES
dc.description.sponsorship The authors are grateful for financial support from the Spanish Government by MAT2014-52085-C2-1-P and Severo Ochoa Excellence Program SEV-2012-0267. A.G. thanks predoctoral fellowships from MINECO for economical support (reference number BES-2012-052429). The European Union is also acknowledged by ERC-AdG-2014-671093-SynCatMatch. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation MINECO/MAT2014-52085-C2-1-P es_ES
dc.relation MINECO/SEV-2012-0267 es_ES
dc.relation ERC/ERC-AdG-2014-671093 es_ES
dc.relation MINECO/BES-2012-052429 es_ES
dc.relation.ispartof Chemistry of Materials es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C-C Bond Forming Reactions and Tandem Processes es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acs.chemmater.6b04563 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gaona Cordero, A.; Díaz Morales, UM.; Corma Canós, A. (2017). Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C-C Bond Forming Reactions and Tandem Processes. Chemistry of Materials. 29(4):1599-1612. https://doi.org/10.1021/acs.chemmater.6b04563 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acs.chemmater.6b04563 es_ES
dc.description.upvformatpinicio 1599 es_ES
dc.description.upvformatpfin 1612 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 29 es_ES
dc.description.issue 4 es_ES
dc.relation.pasarela S\358640 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder European Research Council es_ES


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