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Gas-Phase Photochemical Overall H2 S Splitting by UV Light Irradiation

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Gas-Phase Photochemical Overall H2 S Splitting by UV Light Irradiation

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dc.contributor.author Garcia-Baldovi, Hermenegildo es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author Ferrer Ribera, Rosa Belén es_ES
dc.contributor.author Mateo-Mateo, Diego es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2018-07-16T06:56:40Z
dc.date.available 2018-07-16T06:56:40Z
dc.date.issued 2017 es_ES
dc.identifier.issn 1864-5631 es_ES
dc.identifier.uri http://hdl.handle.net/10251/105850
dc.description.abstract [EN] Splitting of hydrogen sulfide is achieved to produce valueadded chemicals. Upon irradiation at 254 nm in the gas phase and in the absence of catalysts or photocatalysts at near room temperature, H2S splits into stoichiometric amounts of H2 and S with a quantum efficiency close to 50%. No influence of the presence of CH4 and CO2 (typical components in natural gas and biogas in which H2S is an unwanted component) on the efficiency of overall H2S splitting was observed. A mechanism for the H2 and S formation is proposed. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and R1) and Generalitat Valenciana (Prometeo 2013-014) is gratefully acknowledged. Thanks are due to Dr. J. A. Agullo-Macia for performing a preliminary experiment. en_EN
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemSusChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Hydrogen production es_ES
dc.subject Hydrogen sulfide es_ES
dc.subject Photochemistry es_ES
dc.subject Quantum yield es_ES
dc.subject UV light es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Gas-Phase Photochemical Overall H2 S Splitting by UV Light Irradiation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cssc.201700294 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F014/ES/SINTESIS DE GRAFENO Y DERIVADOS COMO SENSORES O CON PROPIEDADES OPTOELECTRONICAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Garcia-Baldovi, H.; Albero-Sancho, J.; Ferrer Ribera, RB.; Mateo-Mateo, D.; Alvaro Rodríguez, MM.; García Gómez, H. (2017). Gas-Phase Photochemical Overall H2 S Splitting by UV Light Irradiation. ChemSusChem. 10(9):1996-2000. https://doi.org/10.1002/cssc.201700294 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/cssc.201700294 es_ES
dc.description.upvformatpinicio 1996 es_ES
dc.description.upvformatpfin 2000 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 10 es_ES
dc.description.issue 9 es_ES
dc.relation.pasarela S\338848 es_ES
dc.contributor.funder Generalitat Valenciana es_ES


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