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dc.contributor.author | Gonell-Gómez, Francisco | es_ES |
dc.contributor.author | Boronat Zaragoza, Mercedes | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2018-07-16T07:26:25Z | |
dc.date.available | 2018-07-16T07:26:25Z | |
dc.date.issued | 2017 | es_ES |
dc.identifier.issn | 2044-4753 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/105878 | |
dc.description.abstract | [EN] The influence of the crystallographic phase of ZrO2 on its catalytic performance in the MPV reduction of cyclohexanone with propan-2-ol has been systematically investigated by combining accurate synthesis procedures, XRD and HRTEM characterization, kinetic measurements and DFT calculations, and compared to that of Zr-beta zeolite. The higher intrinsic activity of monoclinic zirconia as compared to other ZrO2 phases is not due to a lower activation energy for the rate-determining step, but to an adequate distribution of reactant fragments on the catalyst surface, indicating a structure-activity relationship for this reaction when catalyzed by ZrO2 and also by Zr-beta zeolite. Inexpensive and stable ZrO2 catalysts for the MPV reaction have been obtained by controlling the crystallographic phase of the synthesized material. | es_ES |
dc.description.sponsorship | This work has been supported by the Spanish Government through the "Severo Ochoa Program" (SEV 2012-0267). The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization. The Red Espanola de Supercomputacion (RES) and Centre de Calcul de la Universitat de Valencia are gratefully acknowledged for computational facilities and technical assistance. F. Gonell is grateful to Ministerio de Educacion, Cultura y Deporte for a PhD grant (AP2010-2748). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | The Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science & Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Electron Microscopy Service of the UPV | |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Structure-reactivity relationship in isolated Zr sites present in Zr-zeolite and ZrO2 for the Meerwein-Ponndorf-Verley reaction | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c7cy00567a | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/ME//AP2010-2748/ES/AP2010-2748/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Gonell-Gómez, F.; Boronat Zaragoza, M.; Corma Canós, A. (2017). Structure-reactivity relationship in isolated Zr sites present in Zr-zeolite and ZrO2 for the Meerwein-Ponndorf-Verley reaction. Catalysis Science & Technology. 7(13):2865-2873. https://doi.org/10.1039/c7cy00567a | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/c7cy00567a | es_ES |
dc.description.upvformatpinicio | 2865 | es_ES |
dc.description.upvformatpfin | 2873 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 7 | es_ES |
dc.description.issue | 13 | es_ES |
dc.relation.pasarela | S\360132 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Ministerio de Educación |