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An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers

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An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers

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dc.contributor.author Dkhili, Samiha es_ES
dc.contributor.author López-Bernabeu, Sara es_ES
dc.contributor.author Kedir, Chahineze Nawel es_ES
dc.contributor.author Huerta, Francisco es_ES
dc.contributor.author Montilla, Francisco es_ES
dc.contributor.author Besbes-Hentati, Salma es_ES
dc.contributor.author Morallon, Emilia es_ES
dc.date.accessioned 2018-10-14T04:30:57Z
dc.date.available 2018-10-14T04:30:57Z
dc.date.issued 2018 es_ES
dc.identifier.uri http://hdl.handle.net/10251/110326
dc.description.abstract [EN] A study on the electrochemical oxidation of piperazine and its electrochemical copolymerization with aniline in acidic medium is presented. It was found that the homopolymerization of piperazine cannot be achieved under electrochemical conditions. A combination of electrochemistry, in situ Fourier transform infrared (FTIR), and ex situ X-ray photoelectron spectroscopy (XPS) spectroscopies was used to characterize both the chemical structure and the redox behavior of an electrochemically synthesized piperazine¿aniline copolymer. The electrochemical sensing properties of the deposited material were also tested against ascorbic acid and dopamine as redox probes. es_ES
dc.description.sponsorship This research was funded by the Spanish Ministerio de Economia y Competitividad and FEDER funds, grant MAT2016-76595-R. The stay of S. Dkhili at the University of Alicante was funded by the Ministry of Higher Education and Scientific Research of Tunisia. es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Copolymer es_ES
dc.subject Polyaniline es_ES
dc.subject Piperazine es_ES
dc.subject FTIR in situ es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.title An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ma11061012 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76595-R/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Dkhili, S.; López-Bernabeu, S.; Kedir, CN.; Huerta, F.; Montilla, F.; Besbes-Hentati, S.; Morallon, E. (2018). An Electrochemical Study on the Copolymer Formed from Piperazine and Aniline Monomers. Materials. 11(6):1-12. https://doi.org/10.3390/ma11061012 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ma11061012 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 12 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 6 es_ES
dc.identifier.eissn 1996-1944 es_ES
dc.identifier.pmid 29904009 en_EN
dc.identifier.pmcid PMC6025326 en_EN
dc.relation.pasarela S\367436 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministère de l'Enseignement Supérieur et de la Recherche Scientifique, Túnez


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