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Metal-Free Photocatalytic Reductive Dehalogenation Using Visible-Light: A Time-Resolved Mechanistic Study

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Metal-Free Photocatalytic Reductive Dehalogenation Using Visible-Light: A Time-Resolved Mechanistic Study

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Martínez-Haya, R.; Miranda Alonso, MÁ.; Marín García, ML. (2017). Metal-Free Photocatalytic Reductive Dehalogenation Using Visible-Light: A Time-Resolved Mechanistic Study. European Journal of Organic Chemistry. (15):2164-2169. doi:10.1002/ejoc.201601494

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/112492

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Title: Metal-Free Photocatalytic Reductive Dehalogenation Using Visible-Light: A Time-Resolved Mechanistic Study
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The reductive dehalogenation of organic bromides has been achieved in the presence of riboflavin (RF) as photocatalyst under visible-light irradiation. Specifically, benzyl bromide (2) and -bromoacetophenone (3) were ...[+]
Subjects: Electron transfer , Photophysics , Reactive intermediates , Redox chemistry , Time-resolved spectroscopy
Copyrigths: Reserva de todos los derechos
Source:
European Journal of Organic Chemistry. (issn: 1434-193X )
DOI: 10.1002/ejoc.201601494
Publisher:
John Wiley & Sons
Publisher version: http://doi.org/10.1002/ejoc.201601494
Description: This is the peer reviewed version of the following article: Martínez-Haya, Rebeca, Miranda Alonso, Miguel Ángel, Marín García, Mª Luisa. (2017). Metal-Free Photocatalytic Reductive Dehalogenation Using Visible-Light: A Time-Resolved Mechanistic Study.European Journal of Organic Chemistry, 15, 2164-2169, which has been published in final form at http://doi.org/10.1002/ejoc.201601494. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
Thanks:
R. M.-H. acknowledges generous support from the Spanish Government (grant SEV-2012-0267). We also thank for support from the Ministerio de Economia y Competitividat (Project CTQ2012-38754-C03-03), the Generalitat Valenciana ...[+]
Type: Artículo

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