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dc.contributor.author | Sabater i Serra, Roser | es_ES |
dc.contributor.author | Kyritsis, A. | es_ES |
dc.contributor.author | Escobar Ivirico, J.L. | es_ES |
dc.contributor.author | Gómez Ribelles, José Luís | es_ES |
dc.contributor.author | Pissis, P. | es_ES |
dc.contributor.author | Salmerón Sánchez, Manuel | es_ES |
dc.date.accessioned | 2019-01-05T21:03:14Z | |
dc.date.available | 2019-01-05T21:03:14Z | |
dc.date.issued | 2011 | es_ES |
dc.identifier.issn | 1292-8941 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/114742 | |
dc.description.abstract | [EN] Poly( ε -caprolactone)/poly(hydroxyethyl acrylate) networks have been investigated by thermally stimulated depolarization currents (TSDC) and differential scanning calorimetry (DSC). The introduction of hydrophilic units (HEA) in the system aiming at tailoring the hydrophilicity of the system results in a series of copolymer networks with microphase separation into hydrophobic/hydrophilic domains. Polycaprolactone (PCL) crystallization is prevented by the topological constraints HEA units imposed in such heterogeneous domains. Moreover, the mobility of the amorphous PCL chains is enhanced as revealed by the main relaxation process which becomes faster. The glass transition of PHEA-rich domains shifts to lower temperatures, as the total amount of PCL in the copolymer increases, due to the presence of PCL units within the same region. The behaviour of the copolymer networks swollen with different content of water has been investigated to analyze the interaction between water molecules and hydrophobic/hydrophilic domains and provide further insights into the molecular structure of the system. | es_ES |
dc.description.sponsorship | RSS acknowledges Generalitat Valenciana for the support through the grant BEST/2008. JLEI acknowledges the support of the Ministerio de Ciencia e Innovacion through the "Campus de Excelencia Internacional" program consistent with Universitat Politecnica de Valencia. The support of the Ministerio de Ciencia e Innovacion through projects MAT2009-14440-C02-01 and MAT2008-06434 is acknowledged. CIBER-BBN is an initiative funded by the VI National R&D&D&i Plan 20082011, Iniciativa Ingenio 2010, Consolider Program, CIBER Actions and financed by the Instituto de Salud Carlos III with assistance from the European Regional Development Fund. | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | SPRINGER | es_ES |
dc.relation.ispartof | The European Physical Journal E | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Caprolactone | es_ES |
dc.subject | Copolymer networks | es_ES |
dc.subject | Heterogeneous domains | es_ES |
dc.subject | Hydrophilic units | es_ES |
dc.subject | Hydroxyethyl acrylate | es_ES |
dc.subject | Molecular mobility | es_ES |
dc.subject | Thermally stimulated depolarization currents | es_ES |
dc.subject | Topological constraints | es_ES |
dc.subject | Water molecule | es_ES |
dc.subject | Copolymerization | es_ES |
dc.subject | Copolymers | es_ES |
dc.subject | Differential scanning calorimetry | es_ES |
dc.subject | Glass transition | es_ES |
dc.subject | Hydrophilicity | es_ES |
dc.subject | Microphase separation | es_ES |
dc.subject | Water content | es_ES |
dc.subject | Polycaprolactone | es_ES |
dc.subject | Biomaterial | es_ES |
dc.subject | Glass | es_ES |
dc.subject | polyester | es_ES |
dc.subject | Polymacon | es_ES |
dc.subject | Polymer | es_ES |
dc.subject | Water | es_ES |
dc.subject | Article | es_ES |
dc.subject | Biophysics | es_ES |
dc.subject | Chemical structure | es_ES |
dc.subject | Chemistry | es_ES |
dc.subject | Crystallization | es_ES |
dc.subject | Heat | es_ES |
dc.subject | Kinetics | es_ES |
dc.subject | Materials testing | es_ES |
dc.subject | Methodology | es_ES |
dc.subject | Temperature | es_ES |
dc.subject | Biocompatible Materials | es_ES |
dc.subject | Calorimetry | es_ES |
dc.subject | Differential Scanning | es_ES |
dc.subject | Hot Temperature | es_ES |
dc.subject | Molecular Structure | es_ES |
dc.subject | Polyesters | es_ES |
dc.subject | Polyhydroxyethyl Methacrylate | es_ES |
dc.subject | Polymers | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.subject.classification | INGENIERIA ELECTRICA | es_ES |
dc.title | Molecular mobility in biodegradable poly(e-caprolactone)/poly(hydroxyethyl acrylate) networks | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1140/epje/i2011-11037-4 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2009-14440-C02-01/ES/Dinamica De Las Proteinas De La Matriz En La Interfase Celula-Material/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//MAT2008-06434/ES/MATERIALES PARA REGENERACION NEURAL Y ANGIOGENESIS EN EL SISTEMA NERVIOSO CENTRAL/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Ingeniería Eléctrica - Departament d'Enginyeria Elèctrica | es_ES |
dc.description.bibliographicCitation | Sabater I Serra, R.; Kyritsis, A.; Escobar Ivirico, J.; Gómez Ribelles, JL.; Pissis, P.; Salmerón Sánchez, M. (2011). Molecular mobility in biodegradable poly(e-caprolactone)/poly(hydroxyethyl acrylate) networks. The European Physical Journal E. 34(4):37-47. https://doi.org/10.1140/epje/i2011-11037-4 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1140/epje/i2011-11037-4 | es_ES |
dc.description.upvformatpinicio | 37 | es_ES |
dc.description.upvformatpfin | 47 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 34 | es_ES |
dc.description.issue | 4 | es_ES |
dc.relation.pasarela | S\202362 | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación | es_ES |
dc.description.references | A.J. Domb, J. Kost, D. Wiseman (Editors), Handbook of Biodegradable Polymers (Gordon and Breach Science Publishers, 1997) | es_ES |
dc.description.references | A. Schindler, R. Jeffcoat, G.L. Kimmel, C.G. Pitt, M.E. Wall, R.A. Zweidinger, Contemporary Topics in Polymer Science, Vol 2, edited by E.M. Pearce, J.R. Schaefgen (Plenum Publication Corp, New York, 1997) p. 251 | es_ES |
dc.description.references | J. Peña, J. Corrales, I. Izquierdo-Barba, A.L. Doadrio, M. Vallet-Regí, Polym. Degrad. Stab. 91, 1424 (2006) | es_ES |
dc.description.references | C.G. Pitt, in Biodegradable Polymers as Drug Delivery Systems, edited by M. Chasin, R. Langer (Marcel Dekker, New York, 1990) | es_ES |
dc.description.references | Y. Boxberg, M. Schmabelrauch, D. Vogt, M. Salmerón Sanchez, G. Gallego Ferrer, M. Monleón Pradas, J. Suay Anton, J. Polym. Sci., Part B: Polym. Phys. 44, 656 (2006) | es_ES |
dc.description.references | R. MacDonald, S. McCarthy, R. Gross, Macromolecules 29, 7356 (1996) | es_ES |
dc.description.references | Y. Ikada, H. Tsuji, Macromol. Rapid. Commun. 21, 117 (2000) | es_ES |
dc.description.references | J.L. Escobar Ivirico, M. Salmerón Sánchez, R. Sabater i Serra, J.M. Meseguer Dueñas, J.L. Gómez Ribelles, M. Monleón Pradas, Macromol. Chem. Phys. 207, 2195 (2006) | es_ES |
dc.description.references | R. Sabater i Serra, J.L. Escobar Ivirico, J.M. Meseguer Dueñas, A. Andrio Balado, J.L. Gómez Ribelles, M. Salmerón Sanchez, Eur. Phys. J. E 22, 293 (2007) | es_ES |
dc.description.references | J. Van Turnhout, Electrets 33, 81 (1980) | es_ES |
dc.description.references | D. Herrera, J.C. Zamora, A. Bello, M. Grimau, E. Laredo, A.J. Muller, T. Lodge, Macromolecules 38, 5109 (2005) | es_ES |
dc.description.references | D. Newman, E. Laredo, A. Bello, A. Grillo, J.L. Feijoo, A. Muller, Macromolecules 42, 5219 (2009) | es_ES |
dc.description.references | M. Salmerón Sánchez, F. Gallego Ferrer, M. Monleón Pradas, J.L. Gómez Ribelles, Macromolecules 36, 860 (2003) | es_ES |
dc.description.references | G. Gallego Ferrer, M. Monleón Pradas, J.L. Gómez Ribelles, P. Pissis, J. Non-Cryst. Solids 235-237, 692 (1998) | es_ES |
dc.description.references | M. Grimau, E. Laredo, M.C. Perez, A. Bello, J. Chem. Phys. 114, 6417 (2001) | es_ES |
dc.description.references | M.C. Hernández, E. Laredo, A. Bello, Macromolecules 35, 7301 (2002) | es_ES |
dc.description.references | E. Laredo, M. Grimau, P. Barriola, A. Bello, A.J. Müller, Polymer 46, 6532 (2005) | es_ES |
dc.description.references | J.L. Gómez Ribelles, M. Monleón Pradas, G. Gallego Ferrer, M. Peidro Torres, V. Pérez Giménez, P. Pissis, A. Kyritsis, J. Polym. Sci., Part B: Polym. Phys. 87, 1587 (1999) | es_ES |
dc.description.references | F. Lednický, J. Janácek, J. Macromol. Sci. Ser. B 5, 335 (1971) | es_ES |
dc.description.references | A. Kyritsis, P. Pissis, J.L. Gómez Ribelles, M. Monleón Pradas, J. Non-Cryst. Solids 172-174, 1041 (1994) | es_ES |
dc.description.references | A. Kyritsis, P. Pissis, J.L. Gómez Ribelles, M. Monleón Pradas, Polym. Sci. Polym. Phys. 32, 1001 (1994) | es_ES |
dc.description.references | P. Pissis, A. Kyritsis, A.A. Konsta, D. Daoukaki, J. Mol. Struct. 479, 163 (1999) | es_ES |
dc.description.references | A. Kyritsis, P. Pissis, J.L. Gómez Ribelles, M. Monleón Pradas, Polym. Gels Networks 3, 445 (1995) | es_ES |
dc.description.references | C. Alvarez, I. Sics, A. Nogales, Z. Denchev, S.S. Funari, T.A. Ezquerra, Polymer 45, 3953 (2004) | es_ES |
dc.description.references | M. Lebourg, J. Suay Antón, J.L. Gómez Ribelles, Eur. Polym. J. 44, 2207 (2008) | es_ES |
dc.description.references | F. Kremer, A. Schönhals, Broadband Dielectric Spectroscopy (Springer, 2003) | es_ES |
dc.description.references | M. Dionisio, M.T. Viciosa, Y. Wang, J. Mano, Macromol. Rapid. Commun. 26, 1423 (2005) | es_ES |
dc.description.references | D. Fukao, Y. Miyamoto, J. Non-Cryst. Solids 212, 208 (1997) | es_ES |
dc.description.references | B. Wunderlich, Progr. Polym. Sci. 28, 383 (2003) | es_ES |
dc.description.references | R. Sabater i Serra, A. Kyritsis, J.L. Escobar Ivirico, A. Andrio Balado, J.L. Gómez Ribelles, P. Pissis, M. Salmerón Sánchez, Colloid Polym. Sci. 288, 555 (2010) | es_ES |
dc.description.references | P. Skoglund, A. Fransson, J. Appl. Polym. Sci. 61, 2455 (1996) | es_ES |
dc.description.references | Advanced thermal analysis (ATHAS), B. Wunderlich, Pure Appl. Chem. 67, 1019 (1995) http://web.utk.edu/~athas/databank/intro.html | es_ES |
dc.description.references | V. Crescenzi, G. Manzini, G. Calzolari, C. Borri, Eur. Polym. J. 8, 449 (1972) | es_ES |
dc.description.references | P.R. Couchman, Macromolecules 11, 1156 (1978) | es_ES |
dc.description.references | G.P. Johari, A. Hallbrucker, E. Mayer, Nature 330, 552 (1987) | es_ES |