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dc.contributor.author | Meseguer-Lloret, S. | es_ES |
dc.contributor.author | Campins-Falcó, P. | es_ES |
dc.contributor.author | Tortajada-Genaro, Luis Antonio | es_ES |
dc.contributor.author | Blasco-Gómez, F. | es_ES |
dc.date.accessioned | 2019-02-06T21:03:53Z | |
dc.date.available | 2019-02-06T21:03:53Z | |
dc.date.issued | 2003 | es_ES |
dc.identifier.issn | 0306-7319 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/116485 | |
dc.description | This is an Author's Accepted Manuscript of an article published in International Journal of Environmental & Analytical Chemistry, 83, 5, 405-416. DOI: 10.1080/0306731031000101383 © Taylor & Francis, available online at: http://doi.org/10.1080/0306731031000101383 | |
dc.description.abstract | [EN] Cr(III) and/or Cr(VI) determinations based on light emission produced by luminol oxidation by hydrogen peroxide in basic aqueous solution catalyzed by Cr(III) were studied in order to diagnose and/or avoid method bias. The calibration step was optimized, and the usefulness of the method for speciating chromium was tested. The use of the standard addition method in the linear interval concentration range made it possible to diagnose the accuracy of the method for real samples. Good results were obtained for several real water samples containing chromium at different concentrations. The proposed protocol made the method traceable with an appropriate certified reference material and with the reference method. | es_ES |
dc.description.sponsorship | The authors are grateful to the DGICYT (Project n PB 97-1387) and to the Generalitat Valenciana (GR-0036) for financial support. | |
dc.language | Inglés | es_ES |
dc.publisher | Taylor & Francis | es_ES |
dc.relation.ispartof | International Journal of Environmental & Analytical Chemistry | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Chromium(III, IV) | es_ES |
dc.subject | Chemiluminescence | es_ES |
dc.subject | Luminol oxidation | es_ES |
dc.subject.classification | QUIMICA ANALITICA | es_ES |
dc.title | A guide to avoid method bias of chromium(III, VI) chemiluminescence determination by luminol-hydrogen peroxide reaction. Application to unknown water samples | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1080/0306731031000101383 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MECD//PB97-1387/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//GR-0036/ | |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Meseguer-Lloret, S.; Campins-Falcó, P.; Tortajada-Genaro, LA.; Blasco-Gómez, F. (2003). A guide to avoid method bias of chromium(III, VI) chemiluminescence determination by luminol-hydrogen peroxide reaction. Application to unknown water samples. International Journal of Environmental & Analytical Chemistry. 83(5):405-416. https://doi.org/10.1080/0306731031000101383 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1080/0306731031000101383 | es_ES |
dc.description.upvformatpinicio | 405 | es_ES |
dc.description.upvformatpfin | 416 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 83 | es_ES |
dc.description.issue | 5 | es_ES |
dc.relation.pasarela | S\28514 | es_ES |
dc.contributor.funder | Generalitat Valenciana | |
dc.contributor.funder | Ministerio de Educación y Cultura | es_ES |