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Fluorescence polarization immunoassay for rapid screening of the pesticides thiabendazole and tetraconazole in wheat

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Fluorescence polarization immunoassay for rapid screening of the pesticides thiabendazole and tetraconazole in wheat

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dc.contributor.author Boroduleva, Anna Yu. es_ES
dc.contributor.author Manclus Ciscar, Juan José es_ES
dc.contributor.author Montoya, Ángel es_ES
dc.contributor.author Eremin, Sergei A. es_ES
dc.date.accessioned 2019-04-07T20:05:57Z
dc.date.available 2019-04-07T20:05:57Z
dc.date.issued 2018 es_ES
dc.identifier.issn 1618-2642 es_ES
dc.identifier.uri http://hdl.handle.net/10251/119053
dc.description.abstract [EN] Fluorescence polarization immunoassays (FPIAs) for thiabendazole and tetraconazole were first developed. Tracers for FPIAs of thiabendazole and tetraconazole were synthesized and the tracers' structures were confirmed by HPLC-MS/MS. The 4-aminomethylfluorescein-labeled tracers allowed achieving the best assay sensitivity and minimum reagent consumption in comparison with aminofluorescein-labeled and alkyldiaminefluoresceinthiocarbamyl-labeled tracers. Measurements of fluorescence polarization were performed using a portable device. The developed FPIA methods were applied for the analysis of wheat. Fast and simple sample preparation technique earlier developed by authors for pesticides was adapted for thiabendazole and tetraconazole. The limits of detection of thiabendazole and tetraconazole in wheat were 20 and 200g/kg, and the lower limits of quantification were 40 and 600g/kg, respectively. The recovery test was performed by two methodsFPIA and HPLC-MS/MS. The results obtained by FPIA correlated well with those obtained by HPLC-MS/MS (r(2)=0.9985 for thiabendazole, r(2)=0.9952 for tetraconazole). Average recoveries of thiabendazole and tetraconazole were 744% and 723% by FPIA, and average recoveries of thiabendazole and tetraconazole were 86 +/- 2% and 74 +/- 1% by HPLC-MS/MS (n=15). es_ES
dc.description.sponsorship The work was financially supported by the Russian Science Foundation (project No. 14-16-00149).
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Analytical and Bioanalytical Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Fungicides es_ES
dc.subject Thiabendazole es_ES
dc.subject Tetraconazole es_ES
dc.subject Fluorescence polarization immunoassay es_ES
dc.subject Wheat es_ES
dc.subject.classification TECNOLOGIA ELECTRONICA es_ES
dc.title Fluorescence polarization immunoassay for rapid screening of the pesticides thiabendazole and tetraconazole in wheat es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s00216-018-1296-z es_ES
dc.relation.projectID info:eu-repo/grantAgreement/RFBR//4-16-00149/
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2019-10-01 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Electrónica - Departament d'Enginyeria Electrònica es_ES
dc.description.bibliographicCitation Boroduleva, AY.; Manclus Ciscar, JJ.; Montoya, Á.; Eremin, SA. (2018). Fluorescence polarization immunoassay for rapid screening of the pesticides thiabendazole and tetraconazole in wheat. Analytical and Bioanalytical Chemistry. 410(26):6923-6934. https://doi.org/10.1007/s00216-018-1296-z es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s00216-018-1296-z es_ES
dc.description.upvformatpinicio 6923 es_ES
dc.description.upvformatpfin 6934 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 410 es_ES
dc.description.issue 26 es_ES
dc.identifier.pmid 30094787
dc.relation.pasarela S\369058 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Russian Science Foundation
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