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Influence of calcium additiions on the compressive strength and microstructure of alkali-activated ceramic sanitaryware

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Influence of calcium additiions on the compressive strength and microstructure of alkali-activated ceramic sanitaryware

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dc.contributor.author Reig, L. es_ES
dc.contributor.author Soriano Martinez, Lourdes es_ES
dc.contributor.author Tashima, M.M. es_ES
dc.contributor.author Borrachero Rosado, María Victoria es_ES
dc.contributor.author Monzó Balbuena, José Mª es_ES
dc.contributor.author Paya Bernabeu, Jorge Juan es_ES
dc.date.accessioned 2019-05-06T20:03:26Z
dc.date.available 2019-05-06T20:03:26Z
dc.date.issued 2018 es_ES
dc.identifier.issn 0002-7820 es_ES
dc.identifier.uri http://hdl.handle.net/10251/120003
dc.description This is the peer reviewed version of the following article: Reig, L., Soriano Martinez, Lourdes, Tashima, M.M., Borrachero Rosado, María Victoria, Monzó Balbuena, José Mª, Paya Bernabeu, Jorge Juan. (2018). Influence of calcium additiions on the compressive strength and microstructure of alkali-activated ceramic sanitaryware.Journal of the American Ceramic Society, 101, null, 3094-3104. DOI: 10.1111/jace.15436 , which has been published in final form at http://doi.org/10.1111/jace.15436. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
dc.description.abstract [EN] The ceramic sanitary-ware market generates large amounts of waste, both during the production process and due to construction and demolition practices. In this paper, the effect of different amounts and calcium sources (calcium hydroxide Ca(OH)2, calcium aluminate cement CAC, Portland cement PC) on the alkaline activation of ceramic sanitary-ware waste (CSW) was assessed. Blended samples were activated with NaOH and sodium silicate solutions and cured for 3 and 7 days at 65°C. The maximum amount of calcium source-type added to the system varied according to its influence on the compactability of the mortars.CSW was physico-chemically characterized and the compressive strength development of activated samples was assessed on the mortars. The nature of the reaction products was analyzed in pastes, by X-ray diffraction, thermogravimetric analysis, infrared spectroscopy and microscopic studies. The results show a great positive influence with the addition of moderate amounts of Ca(OH)2, PC and CAC on the mechanical properties. Among the typical hydrates usually observed in plain water-hydrated PC or CAC, only AH3 and a small amount of C3AH6 were identified in the alkali-activated CSW/CAC blended pastes, which indicates that Al and Ca from PC, CAC and Ca(OH)2 are taken up in the newly formed (N,C)-A-S-H or C-A-S-H gels. es_ES
dc.description.sponsorship Spanish Ministry of Science and Innovation, Grant/Award Number: APLIGEO BIA2015-70107-R, GEOCEDEM BIA 2011-26947; Electron Microscopy Service of the Universitat Politecnica de Valencia; FEDER es_ES
dc.language Inglés es_ES
dc.publisher Blackwell Publishing es_ES
dc.relation.ispartof Journal of the American Ceramic Society es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alkali activation es_ES
dc.subject Cements es_ES
dc.subject Geopolymers es_ES
dc.subject Mechanical properties es_ES
dc.subject Microstructure es_ES
dc.subject.classification INGENIERIA DE LA CONSTRUCCION es_ES
dc.title Influence of calcium additiions on the compressive strength and microstructure of alkali-activated ceramic sanitaryware es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1111/jace.15436 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//BIA2015-70107-R/ES/APLICACIONES DE SISTEMAS GEOPOLIMERICOS OBTENIDOS A PARTIR DE MEZCLAS DE RESIDUOS: MORTEROS,HORMIGONES Y ESTABILIZACION DE SUELOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//BIA2011-26947/ES/REUTILIZACION DE RESIDUOS CERAMICOS Y DE DEMOLICION EN LA PREPARACION DE NUEVOS MATERIALES GEOPOLIMERICOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.date.embargoEndDate 2019-07-01 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Ciencia y Tecnología del Hormigón - Institut de Ciència i Tecnologia del Formigó es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería de la Construcción y de Proyectos de Ingeniería Civil - Departament d'Enginyeria de la Construcció i de Projectes d'Enginyeria Civil es_ES
dc.description.bibliographicCitation Reig, L.; Soriano Martinez, L.; Tashima, M.; Borrachero Rosado, MV.; Monzó Balbuena, JM.; Paya Bernabeu, JJ. (2018). Influence of calcium additiions on the compressive strength and microstructure of alkali-activated ceramic sanitaryware. Journal of the American Ceramic Society. 101:3094-3104. https://doi.org/10.1111/jace.15436 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1111/jace.15436 es_ES
dc.description.upvformatpinicio 3094 es_ES
dc.description.upvformatpfin 3104 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 101 es_ES
dc.relation.pasarela S\374301 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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