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dc.contributor.author | Margarit Benavent, Vicente Juan | es_ES |
dc.contributor.author | Díaz-Rey, Maria Del Rocio | es_ES |
dc.contributor.author | Navarro Villalba, Mª Teresa | es_ES |
dc.contributor.author | Martínez, Cristina | es_ES |
dc.contributor.author | Corma Canós, Avelino | es_ES |
dc.date.accessioned | 2019-06-14T20:41:42Z | |
dc.date.available | 2019-06-14T20:41:42Z | |
dc.date.issued | 2018 | es_ES |
dc.identifier.issn | 1433-7851 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/122225 | |
dc.description.abstract | [EN] Ferrierite zeolites with nanosized crystals and external surface areas higher than 250m(2)g(-1) have been prepared at relatively low synthesis temperature (120 degrees C) by means of the collaborative effect of two organic structure directing agents (OSDA). In this way, hierarchical porosity is achieved without the use of post-synthesis treatments that usually involve leaching of Tatoms and solid loss. Adjusting the synthesis conditions it is possible to decrease the crystallite size in the directions of the 8- and 10-ring channels, [010] and [001] respectively, reducing their average pore length to 10-30nm and increasing the number of pores accessible. The small crystal size of the nano-ferrierites results in an improved accessibility of reactants to the catalytic active centers and enhanced product diffusion, leading to higher conversion and selectivity with lower deactivation rates for the oligomerization of 1-pentene into longer-chain olefins. | es_ES |
dc.description.sponsorship | This work has been supported by the European Union through the European Research Council (ERC-AdG-2014-671093, SynCatMatch) the Spanish government through the "Severo Ochoa Program" (SEV-2016-0683) and CTQ2015-70126-R, and by the Fundacion Ramon Areces through a research project within the "Life and Materials Sciences" program. M.R.D.-R. acknowledges "La Caixa-Severo Ochoa" International PhD Fellowships (call 2015). The Electron Microscopy Service of the Universitat Politecnica de Valencia is acknowledged for its help in sample characterization. We thank Dr. Manuel Moliner for helpful discussions. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | John Wiley & Sons | es_ES |
dc.relation.ispartof | Angewandte Chemie International Edition | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Ferrierite [FER] | es_ES |
dc.subject | Heterogeneous catalysis | es_ES |
dc.subject | Oligomerization | es_ES |
dc.subject | Structure-directing agents | es_ES |
dc.subject | Zeolites | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1002/anie.201711418 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Margarit Benavent, VJ.; Díaz-Rey, MDR.; Navarro Villalba, MT.; Martínez, C.; Corma Canós, A. (2018). Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior. Angewandte Chemie International Edition. 57(13):3459-3463. https://doi.org/10.1002/anie.201711418 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://doi.org/10.1002/anie.201711418 | es_ES |
dc.description.upvformatpinicio | 3459 | es_ES |
dc.description.upvformatpfin | 3463 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 57 | es_ES |
dc.description.issue | 13 | es_ES |
dc.identifier.pmid | 29485242 | |
dc.relation.pasarela | S\355669 | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |