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Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior

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Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior

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dc.contributor.author Margarit Benavent, Vicente Juan es_ES
dc.contributor.author Díaz-Rey, Maria Del Rocio es_ES
dc.contributor.author Navarro Villalba, Mª Teresa es_ES
dc.contributor.author Martínez, Cristina es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2019-06-14T20:41:42Z
dc.date.available 2019-06-14T20:41:42Z
dc.date.issued 2018 es_ES
dc.identifier.issn 1433-7851 es_ES
dc.identifier.uri http://hdl.handle.net/10251/122225
dc.description.abstract [EN] Ferrierite zeolites with nanosized crystals and external surface areas higher than 250m(2)g(-1) have been prepared at relatively low synthesis temperature (120 degrees C) by means of the collaborative effect of two organic structure directing agents (OSDA). In this way, hierarchical porosity is achieved without the use of post-synthesis treatments that usually involve leaching of Tatoms and solid loss. Adjusting the synthesis conditions it is possible to decrease the crystallite size in the directions of the 8- and 10-ring channels, [010] and [001] respectively, reducing their average pore length to 10-30nm and increasing the number of pores accessible. The small crystal size of the nano-ferrierites results in an improved accessibility of reactants to the catalytic active centers and enhanced product diffusion, leading to higher conversion and selectivity with lower deactivation rates for the oligomerization of 1-pentene into longer-chain olefins. es_ES
dc.description.sponsorship This work has been supported by the European Union through the European Research Council (ERC-AdG-2014-671093, SynCatMatch) the Spanish government through the "Severo Ochoa Program" (SEV-2016-0683) and CTQ2015-70126-R, and by the Fundacion Ramon Areces through a research project within the "Life and Materials Sciences" program. M.R.D.-R. acknowledges "La Caixa-Severo Ochoa" International PhD Fellowships (call 2015). The Electron Microscopy Service of the Universitat Politecnica de Valencia is acknowledged for its help in sample characterization. We thank Dr. Manuel Moliner for helpful discussions. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ferrierite [FER] es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Oligomerization es_ES
dc.subject Structure-directing agents es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.201711418 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Margarit Benavent, VJ.; Díaz-Rey, MDR.; Navarro Villalba, MT.; Martínez, C.; Corma Canós, A. (2018). Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior. Angewandte Chemie International Edition. 57(13):3459-3463. https://doi.org/10.1002/anie.201711418 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/anie.201711418 es_ES
dc.description.upvformatpinicio 3459 es_ES
dc.description.upvformatpfin 3463 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 57 es_ES
dc.description.issue 13 es_ES
dc.identifier.pmid 29485242
dc.relation.pasarela S\355669 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES


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