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Nanolayered Cobalt-Molybdenum Sulfides as Highly Chemo- and Regioselective Catalysts for the Hydrogenation of Quinoline Derivatives

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Nanolayered Cobalt-Molybdenum Sulfides as Highly Chemo- and Regioselective Catalysts for the Hydrogenation of Quinoline Derivatives

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dc.contributor.author Sorribes, Ivan es_ES
dc.contributor.author Liu, Lichen es_ES
dc.contributor.author Doménech Carbó, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2019-06-14T20:41:49Z
dc.date.available 2019-06-14T20:41:49Z
dc.date.issued 2018 es_ES
dc.identifier.issn 2155-5435 es_ES
dc.identifier.uri http://hdl.handle.net/10251/122228
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/acscatal.7b04260
dc.description.abstract [EN] Herein, a general protocol for the preparation of a broad range of valuable N-heterocyclic products by hydrogenation of quinolines and related N-heteroarenes is described. Interestingly, the catalytic hydrogenation of the N-heteroarene ring is chemoselectively performed when other facile reducible functional groups, including alkenes, ketones, cyanides, carboxylic acids, esters, and amides, are present. The key to successful catalysis relies on the use of a nanolayered cobalt-molybdenum sulfide catalyst hydrothermally synthesized from earth-abundant metal precursors. This heterogeneous system displays a tunable composition of phases that allows for catalyst regeneration. Its catalytic activity depends on the composition of the mixed phase of cobalt sulfides, being higher with the presence of Co3S4, and could also be associated with the presence of transient Co-Mo-S structures that mainly vanish after the first catalytic run. es_ES
dc.description.sponsorship Financial support by the Spanish Government-MINECO through the program "Severo Ochoa" (SEV-2016-0683) is gratefully acknowledged. I.S. also thanks the Spanish Government-MINECO for a "Formacion Postdoctoral" fellowship and Vice-Rectorate for Research, Innovation and Transfer of the Universitat Politecnica de Valencia (UPV) for a postdoctoral fellowship. The authors also thank the Microscopy Service of UPV for kind help with TEM and STEM measurements. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation MINECO/SEV-2016-0683 es_ES
dc.relation.ispartof ACS Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Chemo-/regioselective hydrogenation es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Quinolines es_ES
dc.subject N-heterocycles es_ES
dc.subject Co-Mo-S catalysts es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Nanolayered Cobalt-Molybdenum Sulfides as Highly Chemo- and Regioselective Catalysts for the Hydrogenation of Quinoline Derivatives es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acscatal.7b04260 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Sorribes, I.; Liu, L.; Doménech Carbó, A.; Corma Canós, A. (2018). Nanolayered Cobalt-Molybdenum Sulfides as Highly Chemo- and Regioselective Catalysts for the Hydrogenation of Quinoline Derivatives. ACS Catalysis. 8(5):4545-4557. https://doi.org/10.1021/acscatal.7b04260 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1021/acscatal.7b04260 es_ES
dc.description.upvformatpinicio 4545 es_ES
dc.description.upvformatpfin 4557 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 5 es_ES
dc.relation.pasarela 385898 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES


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